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Synthesis of chiral 1,2-diamines from α-pinene and their use in asymmetric nitroaldol reaction

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Abstract

Chiral diamines with C 1 and C 2 symmetry have been synthesized from 2-hydroxypinan-3-one and tested as ligands in Cu-catalyzed asymmetric nitroaldol reaction of nitromethane with 4-nitrobenzaldehyde.

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Authors and Affiliations

  1. Institute of Chemistry, Komi Research Center, Ural Branch, Russian Academy of Sciences, ul. Pervomaiskaya 48, Syktyvkar, 167982, Russia

    I. A. Dvornikova, E. V. Buravlev, I. Yu. Chukicheva & A. V. Kutchin

  2. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, Moscow, 119991, Russia

    K. Yu. Suponitskii

Authors
  1. I. A. Dvornikova
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  2. E. V. Buravlev
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  3. K. Yu. Suponitskii
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  4. I. Yu. Chukicheva
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  5. A. V. Kutchin
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Corresponding author

Correspondence to I. A. Dvornikova.

Additional information

Original Russian Text © I.A. Dvornikova, E.V. Buravlev, K.Yu. Suponitskii, I.Yu. Chukicheva, A.V. Kutchin, 2015, published in Zhurnal Organicheskoi Khimii, 2015, Vol. 51, No. 4, pp. 498–509.

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Dvornikova, I.A., Buravlev, E.V., Suponitskii, K.Y. et al. Synthesis of chiral 1,2-diamines from α-pinene and their use in asymmetric nitroaldol reaction. Russ J Org Chem 51, 480–492 (2015). https://doi.org/10.1134/S1070428015040041

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  • DOI: https://doi.org/10.1134/S1070428015040041

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