Abstract
Reactions of thiophosphoryl isothiocyanates with 3-(triethoxysilyl)propan-1-amine afforded new thiophosphorylated thioureas containing a triethoxysilyl group. The formation of 2: 1 complexes of 1-(di-butoxythiophosphoryl)-3-(3-triethoxysilylpropyl)thiourea with Co(II), Ni(II), and Zn(II) acetates was detected by MALDI mass spectrometry. The copper(II) complex underwent reduction to copper(I) during the recording of the MALDI mass spectrum, and signals from cluster ions [3M − 3H + 4Cu]+ were observed.
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Dedicated to Full Member of the Russian Academy of Sciences V.I. Minkin on his 80th anniversary
Original Russian Text © L.I. Vagapova, D.R. Sharafutdinova, A.R. Burilov, A.R. Mustafina, V.M. Babaev, I.Kh. Rizvanov, M.A. Pudovik, 2015, published in Zhurnal Organicheskoi Khimii, 2015, Vol. 51, No. 3, pp. 327–330.
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Vagapova, L.I., Sharafutdinova, D.R., Burilov, A.R. et al. Synthesis and properties of new thiophosphorylated thioureas containing a trialkoxysilyl group. Russ J Org Chem 51, 309–312 (2015). https://doi.org/10.1134/S1070428015030033
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DOI: https://doi.org/10.1134/S1070428015030033