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Synthesis of fullerene Γ-lactones by free radical reaction of C60 with ketones promoted by compounds of transition metals Cr(VI), Ce(IV)

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Abstract

One-step synthesis was developed for fullerene Γ-lactones by the reaction of C60 with aromatic and aliphatic ketones in the presence of transition metal compounds CrO3, K2Cr2O7, (NH4)2Ce(NO3)6 ·6H2O.

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Authors and Affiliations

  1. Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, pr. Oktyabrya 141, Ufa, 450075, Russia

    R. G. Bulgakov & Z. S. Kinzyabaeva

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  1. R. G. Bulgakov
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  2. Z. S. Kinzyabaeva
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Correspondence to R. G. Bulgakov.

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Original Russian Text © R.G. Bulgakov, Z.S. Kinzyabaeva, 2014, published in Zhurnal Organicheskoi Khimii, 2014, Vol. 50, No. 8, pp. 1206–1210.

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Bulgakov, R.G., Kinzyabaeva, Z.S. Synthesis of fullerene Γ-lactones by free radical reaction of C60 with ketones promoted by compounds of transition metals Cr(VI), Ce(IV). Russ J Org Chem 50, 1189–1193 (2014). https://doi.org/10.1134/S107042801408020X

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  • DOI: https://doi.org/10.1134/S107042801408020X

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