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Reactions of diols with dimethyl carbonate in the presence of W(CO)6 and Co2(CO)8

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Abstract

Dimethoxyalkanes and dimethyl alkanediyl biscarbonates were synthesized by reactions of diols with dimethyl carbonate in the presence of tungsten and cobalt carbonyls. Optimal reactant and catalyst ratios and reaction conditions were found to ensure selective formation of dimethoxyalkanes or dimethyl alkanediyl biscarbonates.

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Authors and Affiliations

  1. Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, pr. Oktyabrya 141, Ufa, 450075, Bashkortostan, Russia

    R. I. Khusnutdinov, N. A. Shchadneva & Yu. Yu. Mayakova

Authors
  1. R. I. Khusnutdinov
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  2. N. A. Shchadneva
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  3. Yu. Yu. Mayakova
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Correspondence to R. I. Khusnutdinov.

Additional information

Original Russian Text © R.I. Khusnutdinov, N.A. Shchadneva, Yu.Yu. Mayakova, 2014, published in Zhurnal Organicheskoi Khimii, 2014, Vol. 50, No. 7, pp. 968–972.

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Khusnutdinov, R.I., Shchadneva, N.A. & Mayakova, Y.Y. Reactions of diols with dimethyl carbonate in the presence of W(CO)6 and Co2(CO)8 . Russ J Org Chem 50, 948–952 (2014). https://doi.org/10.1134/S1070428014070057

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  • DOI: https://doi.org/10.1134/S1070428014070057

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