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Cyclopropane intermediates in the synthesis of chiral alcohols with methyl-branched carbon skeleton. Application in the synthesis of insect pheromones

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Abstract

Several chiral building blocks, (2R)-2-methylundec-10-en-1-ol, (3R)-3-methylheptan-1-ol, and (4R)-4-methyloctan-1-ol, have been synthesized using cyclopropane intermediate products. It has been shown that the obtained chiral alcohols can be used in the synthesis of insect pheromones.

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Authors and Affiliations

  1. Belarusian State University, pr. Nezavisimosti 4, Minsk, 220030, Belarus

    V. N. Kovalenko & I. V. Mineeva

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  1. V. N. Kovalenko
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  2. I. V. Mineeva
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Correspondence to I. V. Mineeva.

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Original Russian Text © V.N. Kovalenko, I.V. Mineeva, 2014, published in Zhurnal Organicheskoi Khimii, 2014, Vol. 50, No. 7, pp. 954–962.

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Kovalenko, V.N., Mineeva, I.V. Cyclopropane intermediates in the synthesis of chiral alcohols with methyl-branched carbon skeleton. Application in the synthesis of insect pheromones. Russ J Org Chem 50, 934–942 (2014). https://doi.org/10.1134/S1070428014070033

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  • DOI: https://doi.org/10.1134/S1070428014070033

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