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Synthesis of alkyl methyl ethers and alkyl methyl carbonates by reaction of alcohols with dimethyl carbonate in the presence of tungsten and cobalt complexes

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Abstract

Alkyl methyl ethers and alkyl methyl carbonates were synthesized by reaction of alcohols with dimethyl carbonate in the presence of tungsten and cobalt carbonyls. Optimal reactant and catalyst ratios, as well as reaction conditions, were found for selective formation of alkyl methyl ethers or alkyl methyl carbonates.

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Authors and Affiliations

  1. Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, pr. Oktyabrya 141, Ufa, 450075, Bashkortostan, Russia

    R. I. Khusnutdinov, N. A. Shchadneva & Yu. Yu. Mayakova

Authors
  1. R. I. Khusnutdinov
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  2. N. A. Shchadneva
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  3. Yu. Yu. Mayakova
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Corresponding author

Correspondence to R. I. Khusnutdinov.

Additional information

Original Russian Text © R.I. Khusnutdinov, N.A. Shchadneva, Yu.Yu. Mayakova, 2014, published in Zhurnal Organicheskoi Khimii, 2014, Vol. 50, No. 6, pp. 808–813.

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Khusnutdinov, R.I., Shchadneva, N.A. & Mayakova, Y.Y. Synthesis of alkyl methyl ethers and alkyl methyl carbonates by reaction of alcohols with dimethyl carbonate in the presence of tungsten and cobalt complexes. Russ J Org Chem 50, 790–795 (2014). https://doi.org/10.1134/S1070428014060050

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  • DOI: https://doi.org/10.1134/S1070428014060050

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