Skip to main content
SpringerLink
Log in

Calix[4]arenes with carboxamide and sulfonamide groups and their complexation with transition metal salts

  • Published:
Russian Journal of Organic Chemistry Aims and scope Submit manuscript

Abstract

Calix[4]arene derivatives functionalized by ester and carboxamide groups on the lower rim and sulfonamide groups on the upper rim were synthesized, and their complexing properties toward transition metal salts (Mn2+, Fe2+, Co2+, Ni2+, Cu2+) were studied by extraction in chloroform-water system. The presence of carboxamide and sulfonamide fragments in the ligand was shown to considerably enhance binding of transition metal cations.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Valero, J. and De Mendoza, J., Supramol. Chem., 2013, vol. 25, p. 728.

    Article  CAS  Google Scholar 

  2. Chawla, H.M., Goel, P., and Shukla, R., Tetrahedron Lett., 2013, vol. 54, p. 2766.

    Article  CAS  Google Scholar 

  3. Bayrakci, M. and Yisiter, S., Tetrahedron, 2013, vol. 69, p. 3218.

    Article  CAS  Google Scholar 

  4. Rudkevich, D.M., Bull. Chem. Soc. Jpn., 2002, vol. 75, p. 393.

    Article  CAS  Google Scholar 

  5. Yang, Y., Lee, E.K., Zhou, H., Surowiec, K., and Bartsch, R.A., J. Inclusion Phenom. Macrocyclic Chem., 2011, vol. 70, p. 197.

    Article  CAS  Google Scholar 

  6. Solovieva, S.E., Muravev, A.A., Zakirzyanov, R.T., Latypov, Sh.K., Antipin, I.S., and Konovalov, A.I., Macroheterocycles, 2012, vol. 5, p. 17.

    Article  CAS  Google Scholar 

  7. Alekseeva, E.A., Basok, S.S., Rakipov, I.M., Mazepa, A.V., and Gren’, A.I., Russ. J. Org. Chem., 2013, vol. 49, p. 1035.

    Article  CAS  Google Scholar 

  8. Mokhtari, V. and Pourabdollah, K., Supramol. Chem., 2012, vol. 24, p. 859.

    Article  CAS  Google Scholar 

  9. Chupakhin, O.N., Itsikson, N.A., Morzherin, Yu.Yu., and Charushin, V.N., Heterocycles, 2005, vol. 66, p. 689.

    Article  CAS  Google Scholar 

  10. Abramov, A.A., Vasiliev, A.N., Dubovaya, O.V., Kovalev, V.V., and Vatsouro, I.M., Mendeleev Commun., 2012, vol. 22, p. 260.

    Article  CAS  Google Scholar 

  11. Calixarenes: A Versatile Class of Macrocyclic Compounds, Vicens, J. and Böhmer, V., Eds., Dordrecht: Kluwer Academic, 1990.

    Google Scholar 

  12. Valiyaveettil, S., Engbersen, J.F.J., Verboom, W., and Reinhoudt, D.N., Angew. Chem., Int. Ed. Engl., 1993, vol. 32, p. 900.

    Article  Google Scholar 

  13. Gutsche, C.D. and Lin, L.-G., Tetrahedron, 1986, vol. 42, p. 1633.

    Article  CAS  Google Scholar 

  14. Morzherin, Yu., Rudkevich, D.M., Verboom, W., and Reinhoudt, D.N., J. Org. Chem., 1993, vol. 58, p. 7602.

    Article  CAS  Google Scholar 

  15. Shinkai, S., Mori, S., Sone, T., and Manade, O., Tetrahedron Lett., 1984, vol. 25, p. 53 158.

    Google Scholar 

  16. Calixarenes 2001, Asfari, Z., Böhmer, V., Harrowfield, J., and Vicens, J., Eds., Dordrecht: Kluwer Academic, 2001.

    Google Scholar 

  17. Coquière, D., Cadeau, H., Rondelez, Y., Giorgi, M., and Reinaud, O., J. Org. Chem., 2006, vol. 71, p. 4059.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Yeltsin Ural Federal University, ul. Mira 19, Yekaterinburg, 620002, Russia

    A. E. Kulyashova, I. V. Geide, P. E. Prokhorova & Yu. Yu. Morzherin

  2. St. Petersburg State University, Universitetskii pr. 26, St. Petersburg, 198504, Russia

    A. E. Kulyashova

Authors
  1. A. E. Kulyashova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. I. V. Geide
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. P. E. Prokhorova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Yu. Yu. Morzherin
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. E. Kulyashova.

Additional information

Original Russian Text © A.E. Kulyashova, I.V. Geide, P.E. Prokhorova, Yu.Yu. Morzherin, 2014, published in Zhurnal Organicheskoi Khimii, 2014, Vol. 50, No. 4, pp. 578–581.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Kulyashova, A.E., Geide, I.V., Prokhorova, P.E. et al. Calix[4]arenes with carboxamide and sulfonamide groups and their complexation with transition metal salts. Russ J Org Chem 50, 567–570 (2014). https://doi.org/10.1134/S1070428014040216

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070428014040216

Keywords

Search

Navigation