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1,2- and 1,4-addition reactions of cycloalkanones with levoglucosenone

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Abstract

The reactions of levoglucosenone with 2-acetylcyclohexanone and 2-acetyldodecanone occurred as tandem Michael addition and 1: 1 aldol condensation to give the corresponding spiro derivatives. Conditions ensuring 1,2- and 1,4-additions of C5–7, 12-cycloalkanones and enamines derived therefrom to levoglucosenone were found.

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Authors and Affiliations

  1. Institute of Organic Chemistry, Ufa Research Center, Russian Academy of Sciences, pr. Oktyabrya 71, Ufa, 450054, Bashkortostan, Russia

    Yu. A. Khalilova, A. R. Tagirov, O. Yu. Doronina, L. V. Spirikhin, Sh. M. Salikhov & F. A. Valeev

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  1. Yu. A. Khalilova
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  2. A. R. Tagirov
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  3. O. Yu. Doronina
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  4. L. V. Spirikhin
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  5. Sh. M. Salikhov
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  6. F. A. Valeev
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Corresponding author

Correspondence to L. V. Spirikhin.

Additional information

Original Russian Text © Yu.A. Khalilova, A.R. Tagirov, O.Yu. Doronina, L.V. Spirikhin, Sh.M. Salikhov, F.A. Valeev, 2014, published in Zhurnal Organicheskoi Khimii, 2014, Vol. 50, No. 1, pp. 118–124.

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Khalilova, Y.A., Tagirov, A.R., Doronina, O.Y. et al. 1,2- and 1,4-addition reactions of cycloalkanones with levoglucosenone. Russ J Org Chem 50, 110–116 (2014). https://doi.org/10.1134/S1070428014010217

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  • DOI: https://doi.org/10.1134/S1070428014010217

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