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Spirocyclic 2,5-dihydro-1H-imidazole 1-oxyl radicals with a mesogenic substituent on C4. Synthesis and crystal structure

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Abstract

Stable spirocyclic 2,5-dihydro-1H-imidazole 1-oxyl radicals containing a mesogenic fragment were synthesized on the basis of 1-[4-hydroxy(alkoxy)phenyl]-2-hydroxyamino-2-methylpropan-1-ones. The crystalline structure of two aminoxyl radicals was determined by X-ray analysis.

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Authors and Affiliations

  1. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent’eva 9, Novosibirsk, 630090, Russia

    E. V. Zaytseva, Yu. V. Gatilov, S. A. Amitina, I. A. Grigor’ev & D. G. Mazhukin

  2. Graduate School of Human and Environmental Studies, Kyoto University, Kyoto, 606-8501, Japan

    R. Tamura

  3. Novosibirsk State University, ul. Pirogova 2, Novosibirsk, 630090, Russia

    D. G. Mazhukin

Authors
  1. E. V. Zaytseva
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  2. Yu. V. Gatilov
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  3. S. A. Amitina
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  4. R. Tamura
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  5. I. A. Grigor’ev
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  6. D. G. Mazhukin
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Corresponding author

Correspondence to E. V. Zaytseva.

Additional information

Original Russian Text © E.V. Zaytseva, Yu.V. Gatilov, S.A. Amitina, R.Tamura, I.A. Grigor’ev, D.G. Mazhukin, 2014, published in Zhurnal Organicheskoi Khimii, 2014, Vol. 50, No. 1, pp. 78–83.

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Zaytseva, E.V., Gatilov, Y.V., Amitina, S.A. et al. Spirocyclic 2,5-dihydro-1H-imidazole 1-oxyl radicals with a mesogenic substituent on C4. Synthesis and crystal structure. Russ J Org Chem 50, 72–77 (2014). https://doi.org/10.1134/S107042801401014X

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  • DOI: https://doi.org/10.1134/S107042801401014X

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