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Synthesis of N-(1,5,3-dithiazepan-3-yl)- and N-(1,5,3-dithiazocan-3-yl)amides in the presence of lanthanide catalysts

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Abstract

A new method was developed for preparation of N-(1,5,3-dithiazepan-5-yl)- and N-(1,5,3-dithiazocan-5-yl)amides by transamination of N-tert-butyl-1,5,3-dithiazepane and N-tert-butyl-1,5,3-dithiazocane, and also by recyclization of 1-oxa-3,6-dithiacycloheptane and 1-oxa-3,7-dithiacyclooctane with carboxylic acids hydrazides in the presence of catalysts based on rare earth elements.

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Authors and Affiliations

  1. Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, Ufa, 450075, Russia

    R. R. Khairullina, B. F. Akmanov, A. G. Ibragimov & U. M. Dzhemilev

  2. Nesmeyanov Institute of Organoelemental Compounds, Russian Academy of Sciences, Moscow, Russia

    Z. A. Starikova

Authors
  1. R. R. Khairullina
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  2. B. F. Akmanov
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  3. Z. A. Starikova
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  4. A. G. Ibragimov
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  5. U. M. Dzhemilev
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Corresponding author

Correspondence to R. R. Khairullina.

Additional information

Original English Text © R.R. Khairullina, B.F. Akmanov, Z.A. Starikova, A.G. Ibragimov, U.M. Dzhemilev, 2013, published in Zhurnal Organicheskoi Khimii, 2013, Vol. 49, No. 11, pp. 1703–1706.

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Khairullina, R.R., Akmanov, B.F., Starikova, Z.A. et al. Synthesis of N-(1,5,3-dithiazepan-3-yl)- and N-(1,5,3-dithiazocan-3-yl)amides in the presence of lanthanide catalysts. Russ J Org Chem 49, 1686–1689 (2013). https://doi.org/10.1134/S1070428013110213

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  • DOI: https://doi.org/10.1134/S1070428013110213

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