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Synthesis of 1-benzyl-3,6-diazahomoadamantane

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Abstract

By condensation of 4-phenylbutan-2-one with tetramethylenediethylenetetramine 1-benzyl-3,6-diazahomoadamantan-9-one was synthesized. Further nitration of 1-benzyl-3,6-diazahomoadamantan-9-one yielded 1-(4-nitrobenzyl)-3,6-diaɛahomoadamantan-9-one. The modification of the nitro and carbonyl groups resulted in the formation of 1-benzyl-3,6-diazahomoadamantane and its derivatives with functional groups in the benzene ring and at the bridge carbon atom C9.

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References

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Authors and Affiliations

  1. Lomonosov Moscow State University of Fine Chemical Technologies, Moscow, 119571, Russia

    A. I. Kuznetsov, I. M. Senan, R. T. Alasadi & A. Kh. Shukkur

  2. Institute of Physiologically Active Compounds, Russian Academy of Sciences, Chernogolovka, Russia

    T. M. Serova

  3. University of Kerbala, Kerbala, Iraq

    R. T. Alasadi

Authors
  1. A. I. Kuznetsov
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  2. I. M. Senan
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  3. R. T. Alasadi
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  4. A. Kh. Shukkur
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  5. T. M. Serova
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Corresponding author

Correspondence to A. I. Kuznetsov.

Additional information

Original English Text © A.I. Kuznetsov, I.M. Senan, R.T. Alasadi, A.Kh. Shukkur, T.M. Serova, 2013, published in Zhurnal Organicheskoi Khimii, 2013, Vol. 49, No. 11, pp. 1683–1686.

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Kuznetsov, A.I., Senan, I.M., Alasadi, R.T. et al. Synthesis of 1-benzyl-3,6-diazahomoadamantane. Russ J Org Chem 49, 1670–1675 (2013). https://doi.org/10.1134/S1070428013110183

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  • DOI: https://doi.org/10.1134/S1070428013110183

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