Abstract
Catalytic chlorination of alkanes, cycloalkanes, and adamantane utilizing tetrachloromethane as the source of chlorine and applying catalysts containing manganese, molybdenum, vanadium, and iron activated with nitrile ligands, alcohols, and water was fulfilled. The optimum ratios of catalysts and reagents and the best reaction conditions were found for selective synthesis of chlorine-substituted hydrocarbons derivatives.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Stteter, V.H., Krause, M., and Last, W.D., Angew. Chem., 1968, p. 970.
Kovacic, P. and Chang, J., J. Org. Chem., 1971, vol. 36, p. 3138.
Schreiner, P.R., Lauenstein, O., Kolomitsin, I.V., and Fokin, A.A., Angew. Chem., Int. Ed., 1998, vol. 37, p. 1895.
Vedernikov, A.N., Scharifullin, R.R., and Solomonov, B.N., Mendeleev Commun., 1996, p. 54.
Vedernikov, A.N., Kuramshin, A.I., Sayakhov, M.D., Sobanov, A.A., and Solomonov, B.N., Russ. J. Org. Chem., 1997, vol. 33, p. 39.
Vedernikov, A.N., Sayakhov, M.D., Zazybin, A.G., and Solomonov, B.N., Russ. J. Org. Chem., 1998, vol. 34, p. 812.
Golubeva, E.N., Nevskaya, S.M., Vorontsov, V.V., and Abdrashitov, Ya.M., Izv. Akad. Nauk, Ser. Khim., 1997, 1835.
Smirnov, V.V., Nevskaya, S.M., and Golubeva, E.N., Neftekhimiya, 2002, vol. 42, p. 22.
Khusnutdinov, R.I., Shchadneva, N.A., Baiguzina, A.R., Lavrent’eva, Yu.Yu., and Dzhemilev, U.M., Izv. Akad. Nauk, Ser. Khim., 2002, p. 1919.
Khusnutdinov, R.I., Shchadneva, N.A., Baiguzina, A.R., and Dzhemilev, U.M., Izv. Akad. Nauk, Ser. Khim., 2002, p. 979.
Smirnov, V.V., Zelikman, V.M., Beletskaya, I.P., Golubeva, E.N., Tsvetkov, D.S., Levitskii, M.M., and Kazankova, M.A., Russ. J. Org. Chem., 2002, vol. 38, p. 1004.
Bagrii, E.I., Adamantany, poluchenie, svoistva, primenenie (Adamantanes: Synthesis, Properties, Application), Moscow: Nauka, 1989.
Khusnutdinov, R.I., Shchadneva, N.A., Baiguzina, A.R., Lavrent’eva, Yu.Yu., Burangulova, R.Yu., and Dzhemilev, U.M., Neftekhimiya, 2004, vol. 44, p. 148.
Fluka. Khimicheskie reaktivy dlya laboratornykh i analiticheskikh rabot (Chemicals for Laboratory and Analytical Researches), Rossiya, 2009–2010, 1748 p.
Aldrich. Catalog. Handbook of Fine Ghemicals, 2009–2010.
Dictionary of Organic Compounds, Buckingham, J., Ed., New York: London-Toronto: Chapman and Hall, 1982.
Asscher, M. and Vofsi, D., J. Am. Chem. Soc., 1961.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original English Text © R.I. Khusnutdinov, N.A. Shchadneva, A.R. Bayguzina, T.M. Oshnyakova, Yu.Yu. Mayakova, U.M. Dzhemilev, 2013, published in Zhurnal Organicheskoi Khimii, 2013, Vol. 49, No. 11, pp. 1583–1591.
Rights and permissions
About this article
Cite this article
Khusnutdinov, R.I., Shchadneva, N.A., Bayguzina, A.R. et al. Chlorination of hydrocarbons with CCl4 catalyzed by complexes of Mn, Mo, V, Fe. Russ J Org Chem 49, 1557–1566 (2013). https://doi.org/10.1134/S1070428013110018
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070428013110018