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Reaction of 3-(alken-1-yl)-4,5-dihydro-3H-pyrazoles with sodium nitrite in acetic acid

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Abstract

3-Vinyl-4,5-dihydro-3H-pyrazole reacted with sodium nitrite in acetic acid to give 3-vinyl-1-nitroso-4,5-dihydro-1H-pyrazole, whereas 3-isopropenyl-4,5-dihydro-3H-pyrazole under analogous conditions was unexpectedly converted into a nitro derivative, 3-(1-methyl-2-nitrovinyl)-4,5-dihydro-1H-pyrazole.

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Authors and Affiliations

  1. Institute of Organic Chemistry, Ufa Research Center, Russian Academy of Sciences, pr. Oktyabrya 71, Ufa, 450054, Bashkortostan, Russia

    K. V. Yakovlev, M. D. Khanova, D. V. Petrov, S. P. Kuleshov & V. A. Dokichev

Authors
  1. K. V. Yakovlev
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  2. M. D. Khanova
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  3. D. V. Petrov
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  4. S. P. Kuleshov
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  5. V. A. Dokichev
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Corresponding author

Correspondence to V. A. Dokichev.

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Original Russian Text © K.V. Yakovlev, M.D. Khanova, D.V. Petrov, S.P. Kuleshov, V.A. Dokichev, 2013, published in Zhurnal Organicheskoi Khimii, 2013, Vol. 49, No. 9, pp. 1367–1368.

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Yakovlev, K.V., Khanova, M.D., Petrov, D.V. et al. Reaction of 3-(alken-1-yl)-4,5-dihydro-3H-pyrazoles with sodium nitrite in acetic acid. Russ J Org Chem 49, 1352–1353 (2013). https://doi.org/10.1134/S1070428013090182

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  • DOI: https://doi.org/10.1134/S1070428013090182

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