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Zirconium-catalyzed reaction of terminal alkenes with triethylindium

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Abstract

Terminal alkenes (undec-1-ene, oct-1-ene, and allylbenzene) reacted with triethylindium in the presence of a catalytic amount of Cp2ZrCl2 in hexane to give mixtures of three organoindium compounds whose hydrolysis in D2O afforded 2-substituted 1,4-dideuterobutane containing minor amounts of 2-substituted 1- and 4-deuterobutanes.

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Authors and Affiliations

  1. Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, pr. Oktyabrya 141, Ufa, 450075, Bashkortostan, Russia

    I. R. Ramazanov, L. K. Dil’mukhametova & U. M. Dzhemilev

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  1. I. R. Ramazanov
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  2. L. K. Dil’mukhametova
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  3. U. M. Dzhemilev
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Correspondence to I. R. Ramazanov.

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Original Russian Text © I.R. Ramazanov, L.K. Dil’mukhametova, U.M. Dzhemilev, 2013, published in Zhurnal Organicheskoi Khimii, 2013, Vol. 49, No. 9, pp. 1271–1274.

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Ramazanov, I.R., Dil’mukhametova, L.K. & Dzhemilev, U.M. Zirconium-catalyzed reaction of terminal alkenes with triethylindium. Russ J Org Chem 49, 1253–1256 (2013). https://doi.org/10.1134/S1070428013090017

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  • DOI: https://doi.org/10.1134/S1070428013090017

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