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Efficient synthesis of 3-aryl(hetaryl)-1,5,3-dioxazepanes involving catalysts containing Sm and Co

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Abstract

Efficient synthetic procedure was developed for 3-aryl(hetaryl)-1,5,3-dioxazepanes consisting in the transamination of 3-tert-butyl-1,5,3-dioxazepane with arylamines and also by the reaction of 1,2-ethanediol with N,N-bis(methoxymethyl)aryl(hetaryl)amines in the presence of catalytic amounts of Sm and Co compounds.

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Authors and Affiliations

  1. Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, Ufa, 450075, Russia

    N. N. Makhmudiyarova, K. I. Prokof’ev, L. V. Mudarisova, A. G. Ibragimov & U. M. Dzhemilev

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  1. N. N. Makhmudiyarova
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  2. K. I. Prokof’ev
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  3. L. V. Mudarisova
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  4. A. G. Ibragimov
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  5. U. M. Dzhemilev
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Correspondence to N. N. Makhmudiyarova.

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Original English Text © N.N. Makhmudiyarova, K.I. Prokof’ev, L.V. Mudarisova, A.G. Ibragimov, U.M. Dzhemilev, 2013, published in Zhurnal Organicheskoi Khimii, 2013, Vol. 49, No. 5, pp. 767–770.

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Makhmudiyarova, N.N., Prokof’ev, K.I., Mudarisova, L.V. et al. Efficient synthesis of 3-aryl(hetaryl)-1,5,3-dioxazepanes involving catalysts containing Sm and Co. Russ J Org Chem 49, 750–753 (2013). https://doi.org/10.1134/S1070428013050217

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  • DOI: https://doi.org/10.1134/S1070428013050217

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