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Carboxyethenylation of polychlorobiphenyls

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Abstract

For the first time 2-carboxyethenylation was performed with butyl acrylate in the presence of palladium catalysts of bromine derivatives of polychlorobiphenyls obtained by bromination of polychlorobiphenyls. The haloderivatives of the butyl phenylcinnamate are readily hydrolyzed and hydrodehalogenized affording a mixture of phenylhydrocinnamic acids.

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References

  1. Gorbunova, T.I., Saloutin, V.I., and Chupakhin, O.N., Usp. Khim., 2010, vol. 79, p. 565.

    Article  Google Scholar 

  2. Gorbunova, T.I., Pervova, M.G., Zabelina, O.N., Saloutin, V.I., and Chupakhin, O.N., Polychlorobiphenyly: problemy ekologii, analiza i khimicheskoi, utilizatsii (Polychlorobiphenyls: Environmnetal Problems, Analysis, and Chemical Disposal), M.oscow KRASAND, 2011.

    Google Scholar 

  3. Wu, B.-Z., Chen, H.-Yu, Wang, Sh.J., Wai, Ch.M., Liao, W., and Chiu, K.-H., Chemosphere, 2012, vol. 88, p. 757.

    Article  CAS  Google Scholar 

  4. Mekhaev, A.V., Chupakhin, O.N., Uimin, M.A., Ermakov, A.E., Pervova, M.G., Gorbunova, T.I., Mysik, A.A., Saloutin, V.I., and Yatluk, Yu.G., Izv. Akad. Nauk, Ser. Khim., 2009, p. 1284.

    Google Scholar 

  5. Mekhaev, A.V., Pervova, M.G., Taran, O.P., Simakova, I.L., Parmon, V.N., Samorukova, M.A., Boyarskii, V.P., Zhesko, T.E., Saloutin, V.I., and Yatluk, Yu.G., Khimiya Interes. Ustoich, Razv., 2011, vol. 19, p. 170.

    Google Scholar 

  6. Beletskaya, I.P. and Cheprakov, A.V., Chem. Rev., 2000, vol. 100, p. 3009.

    Article  CAS  Google Scholar 

  7. Bochmann, M., Creaser, C.S., and Wallace, L., J. Mol. Catal., 1990, vol. 60, p. 343.

    Article  CAS  Google Scholar 

  8. Kirichenko, V.E., Pervova, M.G. Promyshlennikova, E.P., and Pashkevich, K.I., Analitika,, Kontrol’, 2000, vol. 4, no. 1, p. 41.

    Google Scholar 

  9. Piterskikh, I.A., Kirichenko, V.E., Pervova, M.G., and Kandakova, V.V., Zav. Lab. Diagnostika Material., 2001, vol. 67, no.8, p. 63.

    CAS  Google Scholar 

  10. Rajesh, K., Somasundaram, M., Saiganesh, R., and Balasubramanian, K.K., J. Org. Chem., 2007, vol. 72, p. 5867.

    Article  CAS  Google Scholar 

  11. Mekhaev, A.V., Pestov, A.V., Slepukhin, P.A., Yatluk, Yu.G., Pervova, M.G., and Samorukova, M.A., Zh/Org. Khim., 2011, vol. 47, p. 1345.

    Google Scholar 

  12. Tsuji, J. and Ohno, K., J. Am. Chem. Soc., 1968, vol. 90, p. 94.

    Article  CAS  Google Scholar 

Download references

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Authors and Affiliations

  1. Postovskii Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences, Yekaterinburg, 620990, Russia

    A. V. Mekhaev, A. V. Pestov, Yu. G. Yatluk, M. G. Pervova & A. A. Panyukova

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  1. A. V. Mekhaev
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  2. A. V. Pestov
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  3. Yu. G. Yatluk
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  4. M. G. Pervova
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  5. A. A. Panyukova
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Correspondence to A. V. Mekhaev.

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Dedicated to Full Member of the Russian Academy of Sciences I.P. Beletskaya on occasion of her jubilee

Original English Text © A.V. Mekhaev, A.V. Pestov, Yu.G. Yatluk, M.G. Pervova, A.A. Panyukova, 2013, published in Zhurnal Organicheskoi Khimii, 2013, Vol. 49, No. 5, pp. 704–708.

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Mekhaev, A.V., Pestov, A.V., Yatluk, Y.G. et al. Carboxyethenylation of polychlorobiphenyls. Russ J Org Chem 49, 691–695 (2013). https://doi.org/10.1134/S1070428013050096

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  • DOI: https://doi.org/10.1134/S1070428013050096

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