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(4R,6R)-6-(hydroxymethyl)-4-methyltetrahydro-2H-pyran-2-one in the synthesis of polyfunctional compounds with the methyl-branched carbon skeleton

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Abstract

A simple and efficient asymmetrical synthesis was performed of a convenient bifunctional building block, methyl (R)-5,5-dimethoxy-3-methylpentanoate and its (S)-enantiomer. The possibility was shown of its application to the synthesis of insect pheromones.

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Authors and Affiliations

  1. Belarus’ State University, Minsk, 220030, Belarus

    I. V. Mineeva

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  1. I. V. Mineeva
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Correspondence to I. V. Mineeva.

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Original English Text © I.V. Mineeva, 2013, published in Zhurnal Organicheskoi Khimii, 2013, Vol. 49, No. 2, pp. 262–267.

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Mineeva, I.V. (4R,6R)-6-(hydroxymethyl)-4-methyltetrahydro-2H-pyran-2-one in the synthesis of polyfunctional compounds with the methyl-branched carbon skeleton. Russ J Org Chem 49, 253–258 (2013). https://doi.org/10.1134/S1070428013020127

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  • DOI: https://doi.org/10.1134/S1070428013020127

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