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Arylation of geminally activated nitroethenes

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Abstract

3-Aryl-2-nitroprop-2-enenitriles and 1,3-diphenyl-2-nitroprop-2-en-1-one reacted with N,N-dimethylaniline to give the corresponding arylation products, 3-aryl-3-(4-dimethylaminophenyl)-2-nitropropanenitriles and 3-(4-dimethylaminophenyl)-1,3-diphenyl-2-nitropropan-1-one, whose structure was confirmed by IR and 1H and 13C-{1H} spectroscopy with the use of 1H-13C HMQC and HMBC heteronuclear correlation techniques.

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Authors and Affiliations

  1. Herzen State Pedagogical University of Russia, nab. r. Moiki 48, St. Petersburg, 191186, Russia

    R. I. Baichurin, N. I. Aboskalova, E. V. Trukhin & V. M. Berestovitskaya

Authors
  1. R. I. Baichurin
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  2. N. I. Aboskalova
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  3. E. V. Trukhin
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  4. V. M. Berestovitskaya
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Correspondence to R. I. Baichurin.

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Original Russian Text © R.I. Baichurin, N.I. Aboskalova, E.V. Trukhin, V.M. Berestovitskaya, 2013, published in Zhurnal Organicheskoi Khimii, 2013, Vol. 49, No. 1, pp. 76–78.

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Baichurin, R.I., Aboskalova, N.I., Trukhin, E.V. et al. Arylation of geminally activated nitroethenes. Russ J Org Chem 49, 67–69 (2013). https://doi.org/10.1134/S1070428013010120

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  • DOI: https://doi.org/10.1134/S1070428013010120

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