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Design of postmetallocene catalytic systems of arylimine type for olefin polymerization: XIV. Synthesis of (N-Allyloxyaryl)salicylaldimine ligands and their complexes with titanium(IV) dichloride

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Abstract

By reaction of salicylaldehydes with bulky substituents in the positions 3 and 5 with o-, m-, and p-allyloxyaniline hydrochlorides in the presence of triethylamine a series of the corresponding (N-aryl)-salicylaldimines was obtained, which with TiCl2(OPr-i)2 afforded complexes of titanium(IV) dichloride L2TiCl2.

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Authors and Affiliations

  1. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, 630090, Russia

    I. I. Oleinik, I. V. Oleinik & G. A. Tolstikov

  2. St. Petersburg Branch of Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia

    S. S. Ivanchev

Authors
  1. I. I. Oleinik
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  2. I. V. Oleinik
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  3. S. S. Ivanchev
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  4. G. A. Tolstikov
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Correspondence to I. I. Oleinik.

Additional information

Original English Text © I.I. Oleinik, I.V. Oleinik, S.S. Ivanchev, G.A. Tolstikov, 2012, published in Zhurnal Organicheskoi Khimii, 2012, Vol. 48, No. 8, pp. 1075–1084.

For Communication XIII, see [1].

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Oleinik, I.I., Oleinik, I.V., Ivanchev, S.S. et al. Design of postmetallocene catalytic systems of arylimine type for olefin polymerization: XIV. Synthesis of (N-Allyloxyaryl)salicylaldimine ligands and their complexes with titanium(IV) dichloride. Russ J Org Chem 48, 1071–1080 (2012). https://doi.org/10.1134/S1070428012080076

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  • DOI: https://doi.org/10.1134/S1070428012080076

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