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Synthesis and stereochemical configuration of diastereomeric inherently chiral calixarenes with ABCH and ABCD type of substitution at the lower rim

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Abstract

By sulfonylation of tetra(p-tert-butyl)-27-propoxy-25-[N-(1-phenylethyl)carbamoylmethoxy]calix[4] arene diastereomeric inherently chiral calixarenes with the ABCH substitution at the lower rim were synthesized and separated by column chromatography. The alkylation of these compounds afforded the corresponding calixarenes with the ABCD substitution type. The absolute configuration of compounds was established by XRD analysis.

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Authors and Affiliations

  1. Institute of Organic Chemistry, National Academy of Sciences of Ukraine, Kyiv-94, 02660, Ukraine

    O. A. Yesypenko, V. I. Boyko, V. V. Pirozhenko & V. I. Kalchenko

  2. STC “Institute of Single Crystals”, National Academy of Sciences of Ukraine, Kharkiv, Ukraine

    O. V. Shishkin & S. V. Shishkina

Authors
  1. O. A. Yesypenko
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  2. V. I. Boyko
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  3. O. V. Shishkin
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  4. S. V. Shishkina
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  5. V. V. Pirozhenko
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  6. V. I. Kalchenko
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Corresponding author

Correspondence to V. I. Boyko.

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Original Russian Text © O.A. Yesypenko, V.I. Boyko, O.V. Shishkin, S.V. Shishkina, V.V. Pirozhenko, V.I. Kalchenko, 2012, published in Zhurnal Organicheskoi Khimii, 2012, Vol. 48, No. 2, pp. 292–299.

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Yesypenko, O.A., Boyko, V.I., Shishkin, O.V. et al. Synthesis and stereochemical configuration of diastereomeric inherently chiral calixarenes with ABCH and ABCD type of substitution at the lower rim. Russ J Org Chem 48, 284–292 (2012). https://doi.org/10.1134/S1070428012020200

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  • DOI: https://doi.org/10.1134/S1070428012020200

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