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Synthesis and spectral parameters of symmetric and unsymmetrical sandwich-like double- and triple-decker lanthanide complexes containing 1-methyltetrabenzooctadehydrocorrin and phthalocyanine fragments

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Abstract

Single- and double-decker lanthanide complexes with 1-methyltetrabenzooctadehydrocorrin were synthesized by reaction of 3-[(1-hydroxy-1-methyl-1H-isoindol-3-yl)methylidene]-2,3-dihydro-1H-isoindol-1-one with hydrazine hydrate in the presence of lanthanide acetates. Heating of the former with phthalonitrile gave unsymmetrical double- and triple-decker complexes containing 1-methyltetrabenzooctadehydrocorrin and phthalocyanine fragments. Spectral properties of the synthesized complexes were studied.

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Authors and Affiliations

  1. Ivanovo State University of Chemical Technology, pr. F. Engel’sa 7, Ivanovo, 153000, Russia

    N. E. Galanin, L. A. Yakubov & G. P. Shaposhnikov

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  1. N. E. Galanin
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  2. L. A. Yakubov
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  3. G. P. Shaposhnikov
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Correspondence to N. E. Galanin.

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Original Russian Text © N.E. Galanin, L.A. Yakubov, G.P. Shaposhnikov, 2011, published in Zhurnal Organicheskoi Khimii, 2011, Vol. 47, No. 6, pp. 923–929.

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Galanin, N.E., Yakubov, L.A. & Shaposhnikov, G.P. Synthesis and spectral parameters of symmetric and unsymmetrical sandwich-like double- and triple-decker lanthanide complexes containing 1-methyltetrabenzooctadehydrocorrin and phthalocyanine fragments. Russ J Org Chem 47, 941–947 (2011). https://doi.org/10.1134/S1070428011060194

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  • DOI: https://doi.org/10.1134/S1070428011060194

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