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Synthesis and photoinitiating properties of N-substituted 2,6-diisopropylanilines

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Abstract

Reactions of 2,6-diisopropylaniline and its 4-bromo and 4-thiocyanato derivatives with methyl iodide in dimethylformamide in the presence of potassium carbonate gave exclusively the corresponding N,N-dimethyl-substituted products. Heating of 2,6-diisopropylaniline and 2,6-diisopropyl-4-thiocyanatoaniline with methyl iodide without a solvent afforded only N-methyl derivatives.

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Authors and Affiliations

  1. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent’eva 9, Novosibirsk, 630090, Russia

    E. F. Kolchina, N. V. Shekleina & V. V. Shelkovnikov

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  1. E. F. Kolchina
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  2. N. V. Shekleina
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  3. V. V. Shelkovnikov
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Correspondence to E. F. Kolchina.

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Original Russian Text © E.F. Kolchina, N.V. Shekleina, V.V. Shelkovnikov, 2011, published in Zhurnal Organicheskoi Khimii, 2011, Vol. 47, No. 6, pp. 842–847.

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Kolchina, E.F., Shekleina, N.V. & Shelkovnikov, V.V. Synthesis and photoinitiating properties of N-substituted 2,6-diisopropylanilines. Russ J Org Chem 47, 855–861 (2011). https://doi.org/10.1134/S1070428011060042

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  • DOI: https://doi.org/10.1134/S1070428011060042

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