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Free radicals: XXVIII. Reaction of 2,4,6-triphenylpyranyl with (diacetoxy-λ3-iodanyl)benzene

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Abstract

The major product of the reaction of 2,4,6-triphenylpyranyl with (diacetoxy-λ3-iodanyl)benzene in acetonitrile and acetone was 2,4,6-triphenylpyrylium acetate. Analogous reaction in isopropyl alcohol resulted in the formation of methane, carbon dioxide, 1,3,5-triphenylpent-2-ene-1,5-dione, 2-benzoyl-3,5-diphenylfuran, 1,3,5-triphenylpenta-2,4-dien-1-one, and a small amount of 2,4,6-triphenylpyrilium acetate.

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Authors and Affiliations

  1. Ogarev Mordovian State University, ul. Bol’shevistskaya 64, Saransk, 430000, Russia

    B. S. Tanaseichuk, M. K. Pryanichnikova, A. A. Burtasov & A. I. Lisina

  2. Nesmeyanov Institute of Organometallic Compounds, Russian Academy of Sciences, ul. Vavilova 28, Moscow, 119991, Russia

    A. V. Dolganov

Authors
  1. B. S. Tanaseichuk
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  2. M. K. Pryanichnikova
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  3. A. A. Burtasov
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  4. A. I. Lisina
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  5. A. V. Dolganov
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Correspondence to B. S. Tanaseichuk.

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Original Russian Text © B.S. Tanaseichuk, M.K. Pryanichnikova, A.A. Burtasov, A.I. Lisina, A.V. Dolganov, 2011, published in Zhurnal Organicheskoi Khimii, 2011, Vol. 47, No. 3, pp. 447–450.

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Tanaseichuk, B.S., Pryanichnikova, M.K., Burtasov, A.A. et al. Free radicals: XXVIII. Reaction of 2,4,6-triphenylpyranyl with (diacetoxy-λ3-iodanyl)benzene. Russ J Org Chem 47, 442–445 (2011). https://doi.org/10.1134/S1070428011030201

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  • DOI: https://doi.org/10.1134/S1070428011030201

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