Abstract
The acid-base equilibrium of hydrogen peroxide in water solutions of cetyltrimethylammonium bromideand the reactivity of hydroxide and peroxide anions with respect to 4-nitrophenyl diethyl phosphate were investigated. In the micelles the acid ionization constant of the hydrogen peroxide increased three-fold. The application of the pseudophase distribution model under the conditions of competitive sorption of HO− and HOO− anions with the micelles of cetyltrimethylammonium bromide to the estimation of the main kinetic parameters of the micellar process was tested.
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Original Russian Text © L.N. Vakhitova, K.V. Matvienko, A.V. Skrypka, N.A. Taran, N.G. Razumova, A.F. Popov, V.A. Savelova, 2009, published in Zhurnal Organicheskoi Khimii, 2009, Vol. 45, No. 8, pp. 1143–1151.
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Vakhitova, L.N., Matvienko, K.V., Skrypka, A.V. et al. Kinetic regularities of micellar catalysis in the dephosphorylation with peroxide anion. Russ J Org Chem 45, 1128–1136 (2009). https://doi.org/10.1134/S107042800908003X
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DOI: https://doi.org/10.1134/S107042800908003X