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Synthesis and properties of diacetylene azides

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Abstract

A three-stage method was developed for the synthesis of diacetylene azides from diacetylene alcohols prepared by Cadiot-Chodkiewicz reaction. By their bromination the corresponding diacetylene bromides were obtained whose azidation resulted in the target diacetylene azides. The attempt was performed to prepare azides of triacetylene series, but the low stability of the synthesized triacetylene alcohols prevented their conversion into the corresponding bromides.

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Authors and Affiliations

  1. St. Petersburg State University, St. Petersburg, 198504, Russia

    I. N. Domnin & L. A. Remizova

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  1. I. N. Domnin
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  2. L. A. Remizova
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Correspondence to I. N. Domnin.

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Original Russian Text © I.N. Domnin, L.A. Remizova, 2009, published in Zhurnal Organicheskoi Khimii, 2009, Vol. 45, No. 8, pp. 1138–1142.

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Domnin, I.N., Remizova, L.A. Synthesis and properties of diacetylene azides. Russ J Org Chem 45, 1123–1127 (2009). https://doi.org/10.1134/S1070428009080028

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  • DOI: https://doi.org/10.1134/S1070428009080028

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