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Porphyrazines of symmetric and unsymmetrical structure with fused fragments of 1,4-bis(2-phenoxyethoxy)benzene and 5,6-diphenylpyrazine. Synthesis and spectral characteristics

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Abstract

By alkylation of 3,6-dihydroxyphthalonitrile with 1-bromo-2-phenoxyethane 3,6-bis(2-phenoxyethoxy) phthalonitrile was obtained. A random condensation of the nitrile with 2,3-dicyano-5,6-diphenylpyrazine in 1-butanol in the presence of lithium 1-butanolate porphyrazines were synthesized of symmetric and unsymmetrical structure, and their spectral characteristics were investigated.

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Authors and Affiliations

  1. Ivanovo State University of Chemical Engineering, Ivanovo, 153000, Russia

    N. E. Galanin & G. P. Shaposhnikov

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  1. N. E. Galanin
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  2. G. P. Shaposhnikov
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Correspondence to N. E. Galanin.

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Original Russian Text © N.E. Galanin, G.P. Shaposhnikov, 2009, published in Zhurnal Organicheskoi Khimii, 2009, Vol. 45, No. 5, pp. 699–704.

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Galanin, N.E., Shaposhnikov, G.P. Porphyrazines of symmetric and unsymmetrical structure with fused fragments of 1,4-bis(2-phenoxyethoxy)benzene and 5,6-diphenylpyrazine. Synthesis and spectral characteristics. Russ J Org Chem 45, 681–686 (2009). https://doi.org/10.1134/S1070428009050066

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  • DOI: https://doi.org/10.1134/S1070428009050066

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