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Synthesis of new macrocyclic lactones and their extraction study

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Abstract

New macrocyclic lactones were synthesized by reaction of 3-bromo-5-(5-tert-butyl-2-hydroxybenzyl)biphenyl-4-ol with appropriate polyethylene glycol-based dicarboxylic acid dichlorides, and their complexes with Mg(ClO4)2·6H2O, Pb(SCN)2, NaClO4·H2O, and KClO4 were prepared. The macrocyclic ligands were evaluated as extractants in the transfer of Li+, Na+, K+, Cu2+, Ni2+, and Hg2+ picrates from aqueous to organic phase.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Sciences and Arts, University of Selçuk, 42031, Konya, Turkey

    M. Bayrakcı & Ş. Ertul

Authors
  1. M. Bayrakcı
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  2. Ş. Ertul
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Correspondence to Ş. Ertul.

Additional information

Published in Russian in Zhurnal Organicheskoi Khimii, 2008, Vol. 44, No. 9, pp. 1400–1405.

The text was submitted by the authors in English.

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Bayrakcı, M., Ertul, Ş. Synthesis of new macrocyclic lactones and their extraction study. Russ J Org Chem 44, 1384–1388 (2008). https://doi.org/10.1134/S1070428008090236

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  • DOI: https://doi.org/10.1134/S1070428008090236

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