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Liquid-phase oxidation of alkyl-substituted cyclohexylbenzenes

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Abstract

The reactivity of alkyl-substituted cyclohexylbenzenes in liquid-phase oxidation was estimated by the k 2/⇃k 6 value which considerably decreased as the number of methyl groups in the substrate molecule increased. The observed difference in the reactivity of the title compounds was attributed to the degree of coplanarity of intermediate radical species.

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Authors and Affiliations

  1. Yaroslavl State Technical University, Moskovskii pr. 88, Yaroslavl, 150023, Russia

    G. N. Koshel’, E. A. Kurganova, E. V. Smirnova, S. G. Koshel’, V. V. Plakhtinskii & M. S. Belysheva

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  1. G. N. Koshel’
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  2. E. A. Kurganova
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  3. E. V. Smirnova
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  4. S. G. Koshel’
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  5. V. V. Plakhtinskii
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  6. M. S. Belysheva
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Corresponding author

Correspondence to G. N. Koshel’.

Additional information

Original Russian Text © G.N. Koshel’, E.A. Kurganova, E.V. Smirnova, S.G. Koshel’, V.V. Plakhtinskii, M.S. Belysheva, 2008, published in Zhurnal Organicheskoi Khimii, 2008, Vol. 44, No. 4, pp. 558–561.

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Koshel’, G.N., Kurganova, E.A., Smirnova, E.V. et al. Liquid-phase oxidation of alkyl-substituted cyclohexylbenzenes. Russ J Org Chem 44, 553–556 (2008). https://doi.org/10.1134/S1070428008040143

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  • DOI: https://doi.org/10.1134/S1070428008040143

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