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Specificity of the reaction of 2,3-dichloro-4,4-dimethoxy-5-(2-methylfuran-3-yl)cyclopent-2-en-1-one with amines

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Abstract

2,3-Dichloro-4,4-dimethoxy-5-(2-methylfuran-3-yl)cyclopent-2-en-1-one reacted with diethyl-and dipropylamines to give products of AdNE replacement of the chlorine atom at the vinylic C3 atom and substitutive opening of the furan ring with simultaneous deprotection of the dimethyl acetal moiety in the 2,3-dichlorocyclopentenone fragment.

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References

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Authors and Affiliations

  1. Institute of Organic Chemistry, Ufa Research Center, Russian Academy of Sciences, pr. Oktyabrya 71, Ufa, 450054, Bashkortostan, Russia

    F. A. Gimalova, E. M. Minnibaeva, E. M. Vyrypaev & M. S. Miftakhov

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  1. F. A. Gimalova
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  2. E. M. Minnibaeva
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  3. E. M. Vyrypaev
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  4. M. S. Miftakhov
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Correspondence to F. A. Gimalova.

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Original Russian Text © F.A. Gimalova, E.M. Minnibaeva, E.M. Vyrypaev, M.S. Miftakhov, 2008, published in Zhurnal Organicheskoi Khimii, 2008, Vol. 44, No. 3, pp. 403–406.

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Gimalova, F.A., Minnibaeva, E.M., Vyrypaev, E.M. et al. Specificity of the reaction of 2,3-dichloro-4,4-dimethoxy-5-(2-methylfuran-3-yl)cyclopent-2-en-1-one with amines. Russ J Org Chem 44, 397–401 (2008). https://doi.org/10.1134/S1070428008030147

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  • DOI: https://doi.org/10.1134/S1070428008030147

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