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5,15-dialkyl-substituted tetrabenzoporphyrins and their zinc complexes. Synthesis and spectral properties

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Abstract

Reactions of phthalimide with capric and stearic acids gave 1-[1-(1-oxo-1H-isoindol-3-yl)nonylidene]-2,3-dihydro-1H-isoindol-3-one and 1-[1-oxo-1H-isoindol-3-yl)heptadecylidene]-2,3-dihydro-1H-isoindol-3-one, respectively. The latter were heated with zinc(II) acetate to obtain zinc complexes of 5,15-dioctyl-and 5,15-dihexadecyltetrabenzoporphyrins. The same complexes were synthesized by reaction of 1-(1-oxo-1H-isoindol-3-ylmethylidene)-2,3-dihydro-1H-isoindol-3-one with capric or stearic acid in the presence of zinc(II) oxide. The corresponding free porphyrin ligands were obtained by treatment of the metal complexes with sulfuric acid.

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Authors and Affiliations

  1. Ivanovo State University of Chemical Technology, pr. F. Engel’sa 7, Ivanovo, 153000, Russia

    N. E. Galanin, L. A. Yakubov, V. E. Maizlish & G. P. Shaposhnikov

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  1. N. E. Galanin
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  2. L. A. Yakubov
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  3. V. E. Maizlish
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  4. G. P. Shaposhnikov
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Correspondence to N. E. Galanin.

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Original Russian Text © N.E. Galanin, L.A. Yakubov, V.E. Maizlish, G.P. Shaposhnikov, 2007, published in Zhurnal Organicheskoi Khimii, 2007, Vol. 43, No. 9, pp. 1407–1411.

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Galanin, N.E., Yakubov, L.A., Maizlish, V.E. et al. 5,15-dialkyl-substituted tetrabenzoporphyrins and their zinc complexes. Synthesis and spectral properties. Russ J Org Chem 43, 1403–1407 (2007). https://doi.org/10.1134/S1070428007090242

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  • DOI: https://doi.org/10.1134/S1070428007090242

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