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Synthesis and design of tetrapyrrole molecular receptors for alkali metal cations

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Abstract

meso-Phenylporphyrins containing at the benzene ring a conformationally labile polyether fragment with a terminal pyridine ring were synthesized, and their spectral and physicochemical properties were studied. The relations found between the spectral parameters of the tetrapyrrole chromophore, on the one hand, and acid-base equilibria and complex formation with alkali metal cations, on the other, showed the possibility for design of porphyrin-based molecular ensembles possessing useful properties.

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Authors and Affiliations

  1. Institute of Solution Chemistry, Russian Academy of Sciences, ul. Akademicheskaya 1, Ivanovo, 153045, Russia

    Yu. B. Ivanova, O. V. Toldina, V. B. Sheinin & N. Zh. Mamardashvili

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  1. Yu. B. Ivanova
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  2. O. V. Toldina
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  3. V. B. Sheinin
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  4. N. Zh. Mamardashvili
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Correspondence to Yu. B. Ivanova.

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Original Russian Text © Yu.B. Ivanova, O.V. Toldina, V.B. Sheinin, N.Zh. Mamardashvili, 2007, published in Zhurnal Organicheskoi Khimii, 2007, Vol. 43, No. 9, pp. 1401–1406.

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Ivanova, Y.B., Toldina, O.V., Sheinin, V.B. et al. Synthesis and design of tetrapyrrole molecular receptors for alkali metal cations. Russ J Org Chem 43, 1397–1402 (2007). https://doi.org/10.1134/S1070428007090230

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  • DOI: https://doi.org/10.1134/S1070428007090230

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