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Efficient procedure for chemoselective N-nitrosation of secondary amines with trichloromelamine-NaNO2

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Abstract

A combination of trichloromelamine and sodium nitrite in the presence of wet silica gel was used as an effective nitrosating agent for the transformation of secondary amines into the corresponding N-nitroso derivatives under mild and heterogeneous conditions in good to excellent yields.

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Authors and Affiliations

  1. Department of Chemistry, College of Science, Kashan University, Kashan, 51167, Iran

    A. Bamoniri & F. Fallah

  2. Chemistry Department, College of Science, Bu-Ali Sina University, Hamadan, Iran

    M. A. Zolfigol

  3. Department of Chemistry, College of Science, Yazd University, Yazd, Iran

    B. F. Mirjalili

Authors
  1. A. Bamoniri
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  2. M. A. Zolfigol
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  3. B. F. Mirjalili
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  4. F. Fallah
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Corresponding author

Correspondence to A. Bamoniri.

Additional information

Published in Russian in Zhurnal Organicheskoi Khimii, 2007, Vol. 43, No. 9, pp. 1397–1400.

The text was submitted by the authors in English.

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Bamoniri, A., Zolfigol, M.A., Mirjalili, B.F. et al. Efficient procedure for chemoselective N-nitrosation of secondary amines with trichloromelamine-NaNO2 . Russ J Org Chem 43, 1393–1396 (2007). https://doi.org/10.1134/S1070428007090229

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  • DOI: https://doi.org/10.1134/S1070428007090229

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