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Reaction of lithiated 2-trimethylsilyl-1,3-dithiane with (±)-pantolactone

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Abstract

Pantolactone methoxymethyl ether reacted with lithiated 2-trimethylsilyl-1,3-dithiane to give the corresponding ketene dithioacetal and formal monoaddition product of silicon-free 2-lithio-1,3-dithiane at a ratio of 2:1. Possible ways of formation of the latter are discussed.

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Authors and Affiliations

  1. Institute of Organic Chemistry, Ufa Research Center, Russian Academy of Sciences, pr. Oktyabrya 71, Ufa, 450054, Bashkortostan, Russia

    V. Z. Vasikov, I. A. Serbaev, A. M. Gimazetdinov & M. S. Miftakhov

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  1. V. Z. Vasikov
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  2. I. A. Serbaev
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  3. A. M. Gimazetdinov
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  4. M. S. Miftakhov
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Additional information

Original Russian Text © V.Z. Vasikov, I.A. Serbaev, A.M. Gimazetdinov, M.S. Miftakhov, 2007, published in Zhurnal Organicheskoi Khimii, 2007, Vol. 43, No. 6, pp. 916–918.

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Vasikov, V.Z., Serbaev, I.A., Gimazetdinov, A.M. et al. Reaction of lithiated 2-trimethylsilyl-1,3-dithiane with (±)-pantolactone. Russ J Org Chem 43, 915–917 (2007). https://doi.org/10.1134/S1070428007060206

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  • DOI: https://doi.org/10.1134/S1070428007060206

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