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Synthesis of dicyclopropanes from 4,7,7-Trimethyl-3-oxabicyclo[4.1.0]hept-4-en-2-one

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Abstract

New optically active dicyclopropanes were synthesized on the basis of transformation products of 4,7,7-trimethyl-3-oxabicyclo[4.1.0]hept-4-en-2-one using dichlorocarbene or sulfoxonium ylide in the key cyclopropanation stages.

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Original Russian Text © V.G. Kasradze, I.I. Gilyazetdinova, O.S. Kukovinets, E.V. Salimova, I.V. Naleukhin, R.A. Zainullin, A.N. Lobov, L.V. Spirikhin, F.Z. Galin, 2007, published in Zhurnal Organicheskoi Khimii, 2007, Vol. 43, No. 6, pp. 838–842.

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Kasradze, V.G., Gilyazetdinova, I.I., Kukovinets, O.S. et al. Synthesis of dicyclopropanes from 4,7,7-Trimethyl-3-oxabicyclo[4.1.0]hept-4-en-2-one. Russ J Org Chem 43, 834–838 (2007). https://doi.org/10.1134/S1070428007060061

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  • DOI: https://doi.org/10.1134/S1070428007060061

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