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Cycloaddition of tertiary amines to fullerene C60, catalyzed by Ti, Zr, and Hf complexes

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Abstract

Cycloaddition of various tertiary amines to fullerene C60 in the presence of Cp2MCl2 complexes (M = Ti, Zr, Hf) in toluene at 20–150°C in 3–48 h leads to the formation of pyrrolofullerenes in high yields.

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Authors and Affiliations

  1. Institute of Petroleum Chemistry and Catalysis, Russian Academy of Sciences, pr. Oktyabrya 141, Ufa, 450075, Bashkortostan, Russia

    U. M. Dzhemilev, A. G. Ibragimov, V. A. D’yakonov & A. R. Tuktarov

  2. Microelectronics and Material Physics Laboratories, University of Oulu, EMPART Research Group of Infotech Oulu, Linnanmaa P.O. Box 4500, Oulu, 90014, Finland

    M. Pudas

Authors
  1. U. M. Dzhemilev
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  2. A. G. Ibragimov
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  3. M. Pudas
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  4. V. A. D’yakonov
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  5. A. R. Tuktarov
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Original Russian Text © U.M. Dzhemilev, A.G. Ibragimov, M. Pudas, V.A. D’yakonov, A.R. Tuktarov, 2007, published in Zhurnal Organicheskoi Khimii, 2007, Vol. 43, No. 3, pp. 373–376.

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Dzhemilev, U.M., Ibragimov, A.G., Pudas, M. et al. Cycloaddition of tertiary amines to fullerene C60, catalyzed by Ti, Zr, and Hf complexes. Russ J Org Chem 43, 370–374 (2007). https://doi.org/10.1134/S1070428007030062

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  • DOI: https://doi.org/10.1134/S1070428007030062

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