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Reactions of thiols

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Abstract

Published data on the reactivity of thiols, specifically C-, N-, P-, and S-sulfanylation reactions, halogenolysis of S-H bond, dealkylation, and oxidation, are reviewed.

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  1. Ukrainian State University of Chemical Technology, pr. Gagarina 8, Dnepropetrovsk, 49005, Ukraine

    I. V. Koval’

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Original Russian Text © I.V. Koval’, 2007, published in Zhurnal Organicheskoi Khimii, 2007, Vol. 43, No. 3, pp. 327–351.

Ivan Koval’ was born in 1942 in Podgorodnoe village, Dnepropetrovsk region. In 1967 he graduated from the Dnepropetrovsk Institute of Chemical Technology; Candidate of chemical sciences since 1970, Doctor of chemical sciences since 1987; In 1995, I. Koval’ was elected a Full Member of the Ukrainian Academy of Technology. I. Koval’ is now head of the Department of Chemical Technology of High-Molecular Compounds at the Ukrainian State University of Chemical Technology, Dnepropetrovsk, Ukraine.

Fields of scientific interest: organoelement chemistry and chemistry of high-molecular compounds. I. Koval’ discovered, developed methods for generation, and thoroughly studied properties of α-sulfenyl N-centered anions. He is author of more than 200 publications, including 20 reviews on modern problems of organoelement chemistry.

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Koval’, I.V. Reactions of thiols. Russ J Org Chem 43, 319–346 (2007). https://doi.org/10.1134/S1070428007030013

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