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Inhibition of intramolecular reactions of (+)-δ-cadinol

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Abstract

(+)-δ-Cadinol is smoothly acetylated with isopropenyl acetate to form the corresponding acetate which is difficultly hydrolyzable in the presence of bases; unlike initial (+)-δ-cadinol, the acetylation product gives no 1,4-and 1,5-epoxy derivatives as by-products in the allylic oxidation and epoxidation reactions.

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References

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Authors and Affiliations

  1. Institute of Organic Chemistry, Ufa Research Center, Russian Academy of Sciences, pr. Oktyabrya 71, Ufa, 450054, Bashkortostan, Russia

    O. Yu. Krasnoslobodtseva, F. A. Valeev & O. V. Shitikova

  2. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavren’eva 9, Novosibirsk, 630090, Russia

    G. A. Tolstikov

Authors
  1. O. Yu. Krasnoslobodtseva
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  2. F. A. Valeev
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  3. O. V. Shitikova
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  4. G. A. Tolstikov
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Additional information

Original Russian Text © O.Yu. Krasnoslobodtseva, F.A. Valeev, O.V. Shitikova, G.A. Tolstikov, 2006, published in Zhurnal Organicheskoi Khimii, 2006, Vol. 42, No. 9, pp. 1341–1343.

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Krasnoslobodtseva, O.Y., Valeev, F.A., Shitikova, O.V. et al. Inhibition of intramolecular reactions of (+)-δ-cadinol. Russ J Org Chem 42, 1321–1324 (2006). https://doi.org/10.1134/S1070428006090119

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  • DOI: https://doi.org/10.1134/S1070428006090119

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