Skip to main content
SpringerLink
Log in

Ionic liquids on the basis of 2,3,4,6,7,8,9,10-octahydropyrimido-[1,2-a]azepine (1,8-diazabicyclo[5.4.0]undec-7-ene)

  • Published:
Russian Journal of Organic Chemistry Aims and scope Submit manuscript

Abstract

New ionic liquids containing alkyl and polyfluoroalkyl substituents and various anions were synthesized from 2,3,4,6,7,8,9,10-octahydropyrimido[1,2-a]azepinium ion (1,8-diazabicyclo[5.4.0]undec-7-en-8-ium). Their NMR spectra and miscibility with water and organic solvents were studied.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Wasserscheid, P. and Keim, W., Angew. Chem., Int. Ed. Engl., 2000, vol. 39, p. 3772.

    Article  CAS  Google Scholar 

  2. Wilkes, J.S., Levisky, J.A., Wilson, R.A., and Hyssey, C.L., Inorg. Chem., 1982, vol. 21, p. 1263.

    Article  CAS  Google Scholar 

  3. Green, L., Hemeon, I., and Singer, R.D., Tetrahedron Lett., 2000, vol. 41, p. 1343.

    Article  CAS  Google Scholar 

  4. Hardacre, Ch., Holbrey, J.D., Katdare, S.P., and Seddon, R.R., Green Chem., 2002, vol. 4, p. 143.

    Article  CAS  Google Scholar 

  5. Bonhote, P., Dias, A-P., Papageorgiou, N., Kalyanasundaram, K., and Gratzel, M., Inorg. Chem., 1996, vol. 35, p. 1168.

    Article  CAS  Google Scholar 

  6. Kitazume, T., Zulfiqar, F., and Tanaka, G., Green Chem., 2000, vol. 2, p. 133.

    Article  CAS  Google Scholar 

  7. Zulfiqar, F. and Kitazume, T., Green Chem., 2000, vol. 2, p. 137.

    Article  CAS  Google Scholar 

  8. McFarlane, D.R., Sun, J., Golding, J., Meakin, P., and Forsyth, M., Electrochim. Acta, 2000, vol. 45, p. 1271.

    Article  CAS  Google Scholar 

  9. Arduengo, A.J., III, Acc. Chem. Res., 1999, vol. 32, p. 913.

    Article  CAS  Google Scholar 

  10. Xu, L., Chen, W., and Xiao, J., Organometallics, 2000, vol. 19, p. 1123.

    Article  CAS  Google Scholar 

  11. Clement, N.D., Cavell, K.J., Jones, K., and Elsevier, C.J., Angew. Chem., Int. Ed., 2004, vol. 43, p. 1277.

    Article  CAS  Google Scholar 

  12. Stang, P.J., Hanack, M., and Subramanian, L.R., Synthesis, 1982, p. 85.

  13. McBee, E.T., Battershell, R.D., and Braendlin, H.P., J. Am. Chem. Soc., 1962, vol. 84, p. 3157.

    Article  CAS  Google Scholar 

  14. Merrigan, T.L., Bates, E.D., Dorman, S.C., and Davis, J.H., Jr., Chem. Commun., 2000, p. 2051.

  15. Singh, R.P., Manandhar, S., and Shreeve, J.M., Tetrahedron Lett., 2002, vol. 43, p. 9497.

    Article  CAS  Google Scholar 

  16. Beard, C.D., Baum, K., and Grakauskas, V., J. Org. Chem., 1973, vol. 38, p. 3673.

    Article  CAS  Google Scholar 

  17. Cohen, W.V., J. Org. Chem., 1961, vol. 26, p. 4021.

    Article  CAS  Google Scholar 

  18. Hansen, R.L., J. Org. Chem., 1965, vol. 30, p. 322.

    Google Scholar 

  19. Hansen, R.L., Fr. Patent no. 1470669, 1967; Chem. Abstr., 1967, vol. 67, p. 63 788.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Favorskii Irkutsk Institute of Chemistry, Siberian Division, Russian Academy of Sciences, ul. Favorskogo 1, Irkutsk, 664033, Russia

    L. L. Tolstikova & B. A. Shainyan

Authors
  1. L. L. Tolstikova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. B. A. Shainyan
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Original Russian Text © L.L. Tolstikova, B.A. Shainyan, 2006, published in Zhurnal Organicheskoi Khimii, 2006, Vol. 42, No. 7, pp. 1085–1091.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Tolstikova, L.L., Shainyan, B.A. Ionic liquids on the basis of 2,3,4,6,7,8,9,10-octahydropyrimido-[1,2-a]azepine (1,8-diazabicyclo[5.4.0]undec-7-ene). Russ J Org Chem 42, 1068–1074 (2006). https://doi.org/10.1134/S1070428006070256

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070428006070256

Keywords

Search

Navigation