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Catalytic synthesis of 1-arylethylphosphonates by the hydrogenation of unsaturated precursors in the presence of chitosan-based palladium catalysts

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Abstract

Three-component silica-supported palladium-containing systems based on chitosan were synthesized and studied by scanning electron microscopy. These systems showed catalytic activity in the hydrogenation (including chemoselective hydrogenation) of α,β-unsaturated phosphonic acids and their esters. Modification of chitosan on the silica surface with glutaraldehyde considerably enhances the stability and activity of the catalyst.

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Authors and Affiliations

  1. Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, Leninskii pr. 47, Moscow, 119991, Russia

    E. D. Finashina, V. I. Isaeva & L. M. Kustov

  2. Faculty of Chemistry, Moscow State University, Vorob’evy gory 1, Moscow, 119992, Russia

    N. S. Gulyukina, G. N. Bondarenko & I. P. Beletskaya

Authors
  1. E. D. Finashina
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  2. V. I. Isaeva
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  3. L. M. Kustov
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  4. N. S. Gulyukina
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  5. G. N. Bondarenko
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  6. I. P. Beletskaya
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Additional information

Original Russian Text © E.D. Finashina, V.I. Isaeva, L.M. Kustov, N.S. Gulyukina, G.N. Bondarenko, I.P. Beletskaya, 2006, published in Zhurnal Organicheskoi Khimii, 2006, Vol. 42, No. 7, pp. 1010–1015.

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Finashina, E.D., Isaeva, V.I., Kustov, L.M. et al. Catalytic synthesis of 1-arylethylphosphonates by the hydrogenation of unsaturated precursors in the presence of chitosan-based palladium catalysts. Russ J Org Chem 42, 990–995 (2006). https://doi.org/10.1134/S1070428006070116

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  • DOI: https://doi.org/10.1134/S1070428006070116

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