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Behavior of Cationic Surfactants in Rubber Latex Coagulation

  • Macromolecular Compounds and Polymeric Materials
  • Published:
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Abstract

The coagulating power of cationic surfactants differing in the length of the radicals was evaluated. Decylpyridinium chloride, dodecylpyridinium chloride, cetylpyridinium bromide, cetyltrimethylammonium bromide, and alkylbenzyldimethylammonium chloride were tested. The coagulant consumption corresponds to the consumption of the commercially used cationic polyelectrolyte, polydiallyldimethylammonium chloride. A hypothesis concerning the disturbing effect of surfactants on the aggregative stability of latex systems was put forward. The surfactant actin mechanism based on micellar-globular interaction was suggested.

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Funding

This work was supported by ongoing institutional funding. No additional grants to carry out or direct this particular research were obtained.

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Authors and Affiliations

  1. Voronezh State University of Engineering Technologies, 394036, Voronezh, Russia

    S. S. Nikulin, E. V. Churilina & V. N. Verezhnikov

  2. Voronezh Institute for Advanced Training of Staff Members of the Fire Department of the Ministry of the Russian Federation for Civil Defense, Emergencies and Elimination of Consequences of Natural Disasters, 394052, Voronezh, Russia

    N. S. Nikulina

Authors
  1. S. S. Nikulin
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  2. N. S. Nikulina
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  3. E. V. Churilina
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  4. V. N. Verezhnikov
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Contributions

E.V. Churilina and V.N. Verezhnikov: coagulation experiments; N.S. Nikulina: determination of the physicomechanical characteristics of rubber stocks and vulcanizates based on them, literature search; S.S. Nikulin: formulation of the research aim, choice of investigation objects and of procedures for latex coagulation experiments.

Corresponding author

Correspondence to E. V. Churilina.

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The authors declare that they have no conflicts of interest.

Additional information

Translated from Zhurnal Prikladnoi Khimii, No. 8, pp. 763–769, August, 2023 https://www.elibrary.ru/VEZFVW

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Nikulin, S.S., Nikulina, N.S., Churilina, E.V. et al. Behavior of Cationic Surfactants in Rubber Latex Coagulation. Russ J Appl Chem 96, 847–852 (2023). https://doi.org/10.1134/S1070427223090033

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  • DOI: https://doi.org/10.1134/S1070427223090033

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