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Synthesis of Clay-Based Catalysts for the Degradation of Polyolefins by Mechanical Activation

  • Catalysis
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Abstract

An assessment was made of the catalytic properties of samples of clay material from the Shebekinskii district of the Belgorod oblast, subjected to mechanical activation during the conversion of a polyolefin–motor oil mixture into liquid hydrocarbons. It was shown that these catalysts under experimental conditions are not capable of converting the polyethylene–motor oil mixture into liquid hydrocarbons, but are very effective in replacing polyethylene with polypropylene. Varying the time of mechanical action on clay materials affects the yield of products of thermocatalytic degradation of polypropylene. The maximum yield of target products (53 wt %) was detected during the thermocatalytic degradation of a polypropylene–motor oil mixture in the presence of a catalyst obtained after grinding the initial clay material for 8 h.

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ACKNOWLEDGMENTS

The research was carried out using the scientific equipment of the Center for Collective Use “Technologies and Materials” of the Belgorod State National Research University.

Funding

This work was supported by ongoing institutional funding. No additional grants to carry out or direct this particular research were obtained.

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Authors and Affiliations

  1. Belgorod State National Research University, 308015, Belgorod, Russia

    L. V. Furda, O. G. Isakulov & O. E. Lebedeva

Authors
  1. L. V. Furda
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  2. O. G. Isakulov
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  3. O. E. Lebedeva
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Contributions

O. E. Lebedeva: formulation of problems, analysis and processing of the results obtained, analysis of literature data; L.V. Furda: selection of research objects, analysis of literature data, conducting experiments on thermocatalytic degradation; preparation of the section Results and Discussion; O.G. Isakulov: preparation of raw materials, production of catalysts based on clay material, carrying out studies of the acid-base properties of the surface of samples of clay material and catalysts based thereon.

Corresponding author

Correspondence to O. E. Lebedeva.

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Additional information

Translated from Zhurnal Prikladnoi Khimii, No. 6, pp. 622–631, June, 2023 https://www.elibrary.ru/SZHLNB

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Furda, L.V., Isakulov, O.G. & Lebedeva, O.E. Synthesis of Clay-Based Catalysts for the Degradation of Polyolefins by Mechanical Activation. Russ J Appl Chem 96, 693–701 (2023). https://doi.org/10.1134/S1070427223060095

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