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Synthesis of SAPO-31 Nanorod in Ethylene Glycol–Water Medium and Its Catalytic Performance in the n-Hexadecane Hydroisomerization

  • Catalysis
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Abstract

Silicoaluminophosphates (SAPOs) molecular sieves with one-dimensional channels as acid component of bifunctional catalysts loading metal have been attracted attention in the field of clean fuel production due to their mild acidity and shape-selectivity. Herein, a series of novel SAPO-31 molecular sieve nanorod aggregations (S31-xEG) were synthesized in an ethylene glycol–water (EG–H2O) crystallization medium, and the morphology and acidity, as well as the location of Si atoms on the framework were adjusted by changing the EG/H2O ratio. The S31–xEG samples exhibit morphology of aggregation composed of nanorods with mean diameter of ~30 nm and length of 3~4 μm, as well as reduced total Brønsted acid density, which is in good linear correlation with the amount of the framework Si atom with Si(1~4Al) chemical environment. The catalytic performances of 0.5Pd/S31 and 0.5Pd/S31-20EG bifunctional catalysts prepared by loading 0.5 wt % Pd on the SAPO-31 (S31) synthesized in the water as crystallization medium and S31–20EG (EG/H2O = 2 : 3) were tested in the n-hexadecane hydroisomerization, respectively, and both catalysts showed high iso-hexadecane yield (~85.0%), while 0.5Pd/S31–20EG demonstrated larger turnover frequency (TOF) value and proportion of mono-branched iso-hexadecane in the thermodynamic control region (at n-hexadecane conversion of ~90%) due to a synergistic catalysis between metal and Brønsted acid sites.

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ACKNOWLEDGMENTS

This work is supported by Intergovernmental International Science and Technology Innovation Cooperation Key Project (2018YFE0108800).

Funding

This work was supported by ongoing institutional funding. No additional grants to carry out or direct this particular research were obtained.

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Authors and Affiliations

  1. National Center for International Research on Catalytic Technology, Key Laboratory of Functional Inorganic Materials Chemistry (Ministry of Education), School of Chemistry and Material Sciences, Heilongjiang University, 150080, Harbin, China

    Yu Zhang, Chunmu Guo, Wei Wang & Wei Wu

  2. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 119991, Moscow, Russia

    A. L. Maximov

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  1. Yu Zhang
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  2. Chunmu Guo
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  3. A. L. Maximov
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  4. Wei Wang
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Correspondence to Wei Wu.

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Co-author A.L. Maksimov claims to be the editor-in-chief of the Journal of Applied Chemistry; the remaining co-authors have no conflict of interest.

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Zhang, Y., Guo, C., Maximov, A.L. et al. Synthesis of SAPO-31 Nanorod in Ethylene Glycol–Water Medium and Its Catalytic Performance in the n-Hexadecane Hydroisomerization. Russ J Appl Chem 96, 354–365 (2023). https://doi.org/10.1134/S1070427223030151

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