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Synthesis and Thermal Stability of Bis-Quaternary Ammonium Ionic Liquids with Inorganic Anions

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Abstract

Bis-Quaternary ammonium ionic liquids―triethylamine derivatives with hexafluorophosphate, tetrafluoroborate, and dicyanamide anions―were synthesized in the study. All compounds were characterized by IR and NMR spectroscopy. Studies of their thermal stability in air in the temperature range of 25–500°C were performed. A mechanism of thermal destruction was proposed.

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REFERENCES

  1. Cole, A.C., Jensen, J.L., Ntai, I., Tran, L.K.T., Weaver, K.J., Forbes, D.C., and Davis, J.H., J. Am. Chem. Soc., 2002, vol. 124, pp. 5962–5963. https://doi.org/10.1021/ja026290w

    Article  CAS  PubMed  Google Scholar 

  2. Gu, Y., Shi, F., and Deng, Y., Catal. Commun., 2003, vol. 4, pp. 597–601. https://doi.org/10.1016/j.catcom.2003.09.004

    Article  CAS  Google Scholar 

  3. Dupont, J. and Spencer, J., Angew. Chem. Int. Ed., 2004, vol. 43, pp. 5296–5297. https://doi.org/10.1002/anie.200460431

    Article  CAS  Google Scholar 

  4. Sun, J., MacFarlane, D.R., and Forsyth, M., Ionics, 1997, vol. 3, pp. 356–362. https://doi.org/10.1007/BF02375710

    Article  CAS  Google Scholar 

  5. Yu, H., Wu, Y.T., Jiang, Y.Y., Zhou, Z., and Zhang, Z-B., New J. Chem., 2009, vol. 33, pp. 2385–2390. https://doi.org/10.1039/B9NJ00330D

    Article  CAS  Google Scholar 

  6. Brown, P., Butts, C., Dyer, R., Eastoe, J., Grillo, I., Guittard, F., Rogers, S., and Heenan, R., Langmuir, 2011, vol. 27, pp. 4563–4571. https://doi.org/10.1021/la200387n

    Article  CAS  PubMed  Google Scholar 

  7. Mahrova, M., Vilas, M., Domínguez, A., Gómez, E., Calvar, N., and Tojo, E., J. Chem. Eng. Data, 2012, vol. 57, pp. 241–248. https://doi.org/10.1021/je200208h

    Article  CAS  Google Scholar 

  8. Zhao, G.Y.; Jiang, T., Gao, H.X., Han, B.X., Huang, J., and Sun, D.H., Green Chem., 2004, vol. 6, pp. 75-77. https://doi.org/10.1039/B309700P

    Article  CAS  Google Scholar 

  9. Abbott, A.P., Capper, G., Davies, D.L., Rasheed, R.K., and Tambyrajah, V., Green Chem., 2002, vol. 4, pp. 24–26. https://doi.org/10.1039/B108431C

    Article  CAS  Google Scholar 

  10. Xu, F., Matsumoto, K., and Hagiwara, R., Dalton Trans., 2012, vol. 41, pp. 3494–3502. https://doi.org/10.1039/c2dt11693f

    Article  CAS  PubMed  Google Scholar 

  11. Koller, T., Rausch, M.H., Schulz, P.S., Berger, M., Wasserscheid, P., Economou, I.G., Leipertz, A., and Fröba, A.P., J. Chem. Eng. Data, 2012, vol. 57, pp. 828–835. https://doi.org/10.1021/je201080c

    Article  CAS  Google Scholar 

  12. Ferenc, W., Walkow-Dziewulska, A., and Sadowski, P., J. Therm. Anal Cal., 2005, vol. 82, pp. 365–371. https://doi.org/10.1007/s10973-005-0904-2.

    Article  CAS  Google Scholar 

  13. Wyrzykowski, D., Maniecki, T., Garda, M., Styczeń, E., and Warnke, Z., J. Therm. Anal. & Cal., 2007, vol. 90, pp. 893–897. https://doi.org/10.1007/s10973-006-8207-9

    Article  CAS  Google Scholar 

  14. Patent RU 2621105 (Publ. 2017).

  15. Chernikova, E.A., Glukhov, L.M., Krasovskiy, V.G., Kustov, L.M., Vorobyeva, M.G., and Koroteev, A.A., Russ. Chem. Rev., 2015, vol. 84, no. 8, pp. 875–890. https://doi.org/10.1070/RCR4510

    Article  CAS  Google Scholar 

  16. Patent RU 2264860 (Publ. 2005). Immobilizovannye ionnye zhidkosti (Immobilized Ionic Liquids).

  17. Pralhad, A. and Ganeshpure, J.D., React. Kinet. Catal. Lett., 2007, vol. 92, no. 1, pp. 69−74. https://doi.org/10.1007/s11144-007-5077-5

    Article  CAS  Google Scholar 

  18. Lin, X., Chapman, V.J., and Grinstaff, M.W, J. Vis. Exp., 2016, vol. 118, ID e54864. https://doi.org/10.3791/5486

    Article  Google Scholar 

  19. Haskins, N.J., Mitchell, R., Analyst, 1991, vol. 116, pp. 901–903. https://doi.org/10.1039/AN9911600901

    Article  CAS  Google Scholar 

  20. Haskins, N.J., Mitchell, R., Analyst, 1991, vol. 116, pp. 901–903. https://doi.org/10.1039/AN9911600901

    Article  CAS  Google Scholar 

  21. Crosthwaite, J.M., Muldoon, M.J, Dixon, J.K., Anderson, J.L., and Brennecke, J.F., J. Chem. Thermodynamics, 2005, vol. 37, no. 6, pp. 559–568. https://doi.org/10.1016/j.jct.2005.03.013

    Article  CAS  Google Scholar 

  22. Hemp, S.T., Zhang, M., Allen, M.H., Cheng, S., Moore, R.B., and Long, T.E., Macromol. Chem. Phys., 2013, vol. 214, pp. 2099−2107. https://doi.org/10.1002/macp.201300322

    Article  CAS  Google Scholar 

  23. Maton, C., Vos, N.D., and Stevens, C.V., Chem. Soc. Rev., 2013, vol. 42, pp. 5963–5977. https://doi.org/10.1039/C3CS60071H

    Article  CAS  PubMed  Google Scholar 

  24. Prasad, M.R.R. and Krishnamurthy, V.N., Thermochim. Acta, 1991, vol. 185, pp. 1–10. https://doi.org/10.1016/0040-6031(91)80112-V

    Article  Google Scholar 

  25. Prasad, M.R.R., Sudhakarbabu, K., Sreedhar, B., and Devi, D.K., J. Therm. Anal. Calorim., 2014, vol. 16, pp. 1027–1031. https://doi.org/10.1007/s10973-013-3558-5

    Article  CAS  Google Scholar 

  26. Sykes, P., A Guidebook to Mechanism in Organic Chemistry, London: Longman, 2007.

    Google Scholar 

  27. Udupa, M.R., Propellants Explos. Pyrotech., 1982, vol. 7, pp. 155-157. https://doi.org/10.1002/prep.19820070605

    Article  CAS  Google Scholar 

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This work was supported by ongoing institutional funding. No additional grants to carry out or direct this particular research were obtained.

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Zhuravlev, O.E., Kaftanov, A.D., Yulmasov, G.S. et al. Synthesis and Thermal Stability of Bis-Quaternary Ammonium Ionic Liquids with Inorganic Anions. Russ J Appl Chem 96, 395–401 (2023). https://doi.org/10.1134/S1070427223030138

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