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N1-, N2-, and N3-Methyl-4-nitro-1,2,3-triazoles and Metal Complexes Based on Them

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Abstract

Alkylation of an NH-heterocycle, 4-nitro-1,2,3-triazole, with dimethyl sulfate is accompanied by tandem alkylation–quaternization and yields a complex mixture of products of N-monoalkylation at all the three heteroatoms, N-1, N-2, and N-3, with the significant prevalence of the N3 derivative and product of its further transformation, 1,3-dimethyl-4-nitro-1,2,3-triazolium salt. Previously unknown complexes of N3-methylnitrotriazole with copper(II) and nickel(II) ions were prepared.

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Funding

The study was performed within the framework of basic budget funding (state registry no. of the project 121061500029-7) using the device base of the Biisk Regional Center for Shared Use, Siberian Branch, Russian Academy of Sciences (Institute for Problems of Chemical and Energetic Technologies, Siberian Branch, Russian Academy of Sciences, Biisk, Altai krai, Russia).

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Authors and Affiliations

  1. Institute for Problems of Chemical and Energetic Technologies, Siberian Branch, Russian Academy of Sciences, Biisk, 659322, Altai krai, Russia

    Yu. V. Filippova, I. A. Krupnova, K. K. Bosov, G. T. Sukhanov, A. G. Sukhanova & E. V. Pivovarova

Authors
  1. Yu. V. Filippova
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  2. I. A. Krupnova
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  3. K. K. Bosov
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  4. G. T. Sukhanov
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  5. A. G. Sukhanova
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  6. E. V. Pivovarova
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Contributions

Yu.V. Filippova, I.A. Krupnova, K.K. Bosov, and E.V. Pivovarova: experimental work, collection, analysis, and interpretation of the results, manuscript preparation, approval of the final version of the paper, and consent to be responsible for all the aspects of the study; G.T. Sukhanov and A.G. Sukhanova: significant contribution to the concept of the study, interpretation of the results, critical revision of the manuscript, approval of the final version of the paper, and consent to be responsible for all the aspects of the study.

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Correspondence to Yu. V. Filippova.

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Filippova, Y.V., Krupnova, I.A., Bosov, K.K. et al. N1-, N2-, and N3-Methyl-4-nitro-1,2,3-triazoles and Metal Complexes Based on Them. Russ J Appl Chem 96, 366–371 (2023). https://doi.org/10.1134/S1070427223030114

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  • DOI: https://doi.org/10.1134/S1070427223030114

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