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Physical-mechanical Properties and Morphology of Lignocellulose Powder Modifiers for Vulcanized Rubbers

  • Macromolecular Compounds and Polymeric Materials
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Abstract

Powder lignocellulose modifiers for vulcanized rubbers were prepared from secondary paper resources (recycled cardboard) treated with TiCl4 in hexane. The diffraction patterns, IR spectra, and morphological characteristics of the materials obtained, including the geometric characteristics and length distribution of fibers, were analyzed. The content of titanium, lignin, and carbonyl and carboxyl groups and the bulk density of the material were determined. The presence of up to 5 wt parts of powder modifiers per 100 wt parts of rubber in the rubber stock favors preservation of physicomechanical properties of vulcanized rubbers both before and after accelerated thermal oxidative aging at 100°C for 72 h, enhancing the resin–metal cord adhesion and thus prolonging the operation life of the vulcanized rubbers.

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ACKNOWLEDGMENTS

The study was performed using the Chemistry Center for Shared Use, Institute of Chemistry, Kola Scientific Center, Ural Branch, Russian Academy of Sciences, Syktyvkar, Komi Republic, Russia and of the Kazan National Research University of Technology, Kazan, Tatarstan, Russia.

The authors are grateful to the Lomonosov Northern (Arctic) Federal University for the analysis of the samples with an L&W automatic fiber tester.

Funding

The study was supported by the Ministry of Science and Higher Education of the Russian Federation (government assignment no. 122040600027-6).

Author information

Authors and Affiliations

  1. Institute of Chemistry, Federal Research Center Komi Scientific Center, Ural Branch, Russian Academy of Sciences, Syktyvkar, 167000, Komi Republic, Russia

    L. A. Kuvshinova & E. V. Udoratina

  2. Kazan National Research University of Technology, Kazan, 420015, Tatarstan, Russia

    Yu. S. Karaseva & E. N. Cherezova

Authors
  1. L. A. Kuvshinova
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  2. E. V. Udoratina
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  3. Yu. S. Karaseva
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  4. E. N. Cherezova
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Correspondence to L. A. Kuvshinova or Yu. S. Karaseva.

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Translated from Zhurnal Prikladnoi Khimii, No. 3, pp. 252–263, August, 2023 https://doi.org/10.31857/S0044461823030039

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Kuvshinova, L.A., Udoratina, E.V., Karaseva, Y.S. et al. Physical-mechanical Properties and Morphology of Lignocellulose Powder Modifiers for Vulcanized Rubbers. Russ J Appl Chem 96, 281–291 (2023). https://doi.org/10.1134/S1070427223030035

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  • DOI: https://doi.org/10.1134/S1070427223030035

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