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Magnesium Hydrogen-generating Materials and a Hydrogen Generation Setup

  • Hydrogen Technologies
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Abstract

The reaction of composites consisting of MgH2 and a graphene-like or nickel–graphene material with water or citric acid solutions of various concentrations was studied. The composites were prepared by mechanochemical treatment in a hydrogen atmosphere. The reaction of an aqueous citric acid solution with the composites is fast: 98% hydrogen yield is reached at the MgH2 : citric acid molar ratio of 1 : 1. A setup for preparing compressed hydrogen from the composites was developed. It can be used in autonomous mobile installations for hydrogen generation under high pressure, followed by filling balloons.

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REFERENCES

  1. Liu, Z., Zhong, J., Leng, H., Xia, G., and Yu, X., Int. J. Hydrogen Energy, 2021, vol. 46, pp. 18988–19000. https://doi.org/10.1016/j.ijhydene.2021.03.063

    Article  CAS  Google Scholar 

  2. Abdelhamid, H.N., Int. J. Hydrogen Energy, 2021, vol. 46, pp. 726–765. https://doi.org/10.1016/j.ijhydene.2020.09.186

    Article  CAS  Google Scholar 

  3. Agrawal, T., Ajitkumar, R., Prakash, R., and Nandan, G., Mater. Today: Proc., 2018, vol. 5, pp. 3563–3570. https://doi.org/10.1016/j.matpr.2017.11.605

    Article  CAS  Google Scholar 

  4. Hiroi, Sh., Hosokai, S., and Akiyama, T., Int. J. Hydrogen Energy, 2011, vol. 36, pp. 1442–1447. https://doi.org/10.1016/j.ijhydene.2010.10.093

    Article  CAS  Google Scholar 

  5. Kravchenko, O.V., Sevastyanova, L.G., Urvanov, S.A., and Bulychev, B.M., Int. J. Hydrogen Energy, 2014, vol. 39, pp. 5522–5527. https://doi.org/10.1016/j.ijhydene.2014.01.181

    Article  CAS  Google Scholar 

  6. Grosjean, M.-H., Zidoune, M., Huot, J.-Y., and Roué, L., Int. J. Hydrogen Energy, 2006, vol. 31, pp. 1159–1163. https://doi.org/10.1016/j.ijhydene.2005.10.001

    Article  CAS  Google Scholar 

  7. Gan, D., Liu, Y., Zhang, J., Zhang, Y., Cao, Ch., Zhu, Y., and Li, L., Int. J. Hydrogen Energy, 2018, vol. 43, pp. 10232–10239. https://doi.org/10.1016/j.ijhydene.2018.04.119

    Article  CAS  Google Scholar 

  8. Hiraki, T., Hiroi, S., Akashi, T., Okinaka, N., and Akiyama, T., Int. J. Hydrogen Energy, 2012, vol. 37, pp. 12114–12119. https://doi.org/10.1016/j.ijhydene.2012.06.012

    Article  CAS  Google Scholar 

  9. Patent US 10239753 B2, Publ. 2019.

  10. Pighin, S.A., Urretavizcaya, G., Bobet, J.-L., and Castro, F.J., J. Alloys Compd., 2020, vol. 827, ID 154000. https://doi.org/10.1016/j.jallcom.2020.154000

    Article  CAS  Google Scholar 

  11. Grosjean, M.-H., Zidoune, M., Roué, L., and Huot, J.-Y., Int. J. Hydrogen Energy, 2006, vol. 31, pp. 109–119. https://doi.org/10.1016/j.ijhydene.2005.01.001

    Article  CAS  Google Scholar 

  12. Tarasov, B.P., Arbuzov, A.A., Mozhzhuhin, S.A., Volodin, A.A., Fursikov, P.V., Lototskyy, M.V., and Yartys, V.A., Int. J. Hydrogen Energy, 2019, vol. 44, pp. 29212–29223. https://doi.org/10.1016/j.ijhydene.2019.02.033

    Article  CAS  Google Scholar 

  13. Lukashev, R.V., Yakovleva, N.A., Klyamkin, S.N., and Tarasov, B.P., Russ. J. Inorg. Chem., 2008, vol. 53, no. 3, pp. 343–349. https://doi.org/10.1134/S0036023608030017

    Article  Google Scholar 

  14. Son, V.B., Shimkus, Yu.Ya., Mozhzhukhin, S.A., Bocharnikov, M.S., Fokina, E.E., and Tarasov, B.P., Russ. J. Appl. Chem., 2020, vol. 93, no. 9, pp. 1380–1386. https://doi.org/10.1134/S1070427220090104

    Article  CAS  Google Scholar 

  15. Arbuzov, A.A., Muradyan, V.E., and Tarasov, B.P., Russ. Chem. Bull., 2013, vol. 62, no. 9, pp. 1962–1966. https://doi.org/10.1007/s11172-013-0284-x

    Article  CAS  Google Scholar 

  16. Patent RU 2660232, Publ. 2018.

  17. Tarasov, B.P., Arbuzov, A.A., Volodin, A.A., Fursikov, P.V., Mozhzhuhin, S.A., Lototskyy, M.V., and Yartys, V.A., J. Alloys Compd., 2022, vol. 896, ID 162881. https://doi.org/10.1016/j.jallcom.2021.162881

    Article  CAS  Google Scholar 

  18. Lur’e, Yu.Yu., Spravochnik po analiticheskoi khimii (Handbook of Analytical Chemistry), Moscow: Khimiya, 1971, p. 251

    Google Scholar 

  19. Kushch, S.D., Kuyunko, N.S., Nazarov, R.S., and Tarasov, B.P., Int. J. Hydrogen Energy, 2011, vol. 36, pp. 1321–1325. https://doi.org/10.1016/j.ijhydene.2010.06.115

    Article  CAS  Google Scholar 

  20. Patent US 7037483 B2, Publ. 2006.

  21. Patent US 8636961 B2, Publ. 2014.

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ACKNOWLEDGMENTS

Equipment of the Analytical Center for Shared Use at the Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences, was used in the study.

Funding

The study was financially supported by the Ministry of Science and Higher Education of the Russian Federation (megagrant, agreement no. 075-15-2022-1126).

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Authors and Affiliations

  1. Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences, Chernogolovka, 142432, Moscow oblast, Russia

    A. A. Arbuzov, S. A. Mozhzhukhin, M. V. Lototskii & B. P. Tarasov

  2. HySA Systems Centre of Competence, University of the Western Cape, 7535, Bellville, South Africa

    M. V. Lototskii

  3. Department of Fundamental Physicochemical Engineering, Moscow State University, 119991, Moscow, Russia

    B. P. Tarasov

  4. Department of Physics, Higher School of Economics, National Research University, 101000, Moscow, Russia

    B. P. Tarasov

Authors
  1. A. A. Arbuzov
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  2. S. A. Mozhzhukhin
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  3. M. V. Lototskii
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  4. B. P. Tarasov
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Corresponding author

Correspondence to A. A. Arbuzov.

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The authors declare that they have no conflict of interest.

Additional information

Translated from Zhurnal Prikladnoi Khimii, No. 2, pp. 217–224, February, 2023 https://doi.org/10.31857/S004446182302010X

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Arbuzov, A.A., Mozhzhukhin, S.A., Lototskii, M.V. et al. Magnesium Hydrogen-generating Materials and a Hydrogen Generation Setup. Russ J Appl Chem 96, 211–217 (2023). https://doi.org/10.1134/S1070427223020120

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