Abstract
The possibility of obtaining polysaccharide esters based on large-scale products of plant origin: inulin and tall oil fatty acids, was studied. Carbohydrate esters of the biopolymer inulin and higher unsaturated acids were synthesized by acylation with acid chlorides under various conditions: in a water–chloroform mixture in the presence of sodium hydroxide and sodium salts of tall oil fatty acids, as well as in a pyridine–1,4-dioxane mixture. The yield of polysaccharide esters was 67–82%, the maximum yield was detected during the acylation of inulin in the pyridine–1,4-dioxane system.
REFERENCES
Ahmad, M.U. and Xu, X., Polar Lipids: Biology, Chemistry, and Technology, Urbana: AOCS Press, 2015. https://doi.org/10.1016/C2015-0-02381-4
Tracy, P., Dasgupta, D., and More, S., Ind. Crops Prod., 2023, vol. 193, ID 116170. https://doi.org/10.1016/j.indcrop.2022.116170
Bhanja, A., Sutar, P.P., and Mishra, M., J. Food Biochem., 2022, vol. 46, no. 12, ID e14386. https://doi.org/10.1111/jfbc.14386
Mensink, M.A., Frijlink, H.W., van der Voort Maarschalk, K., and Hinrichs, W.L.J., Carbohydr. Polym., 2015, vol. 130, pp. 405–419. https://doi.org/10.1016/j.carbpol.2015.05.026
Stevens, C.V., Meriggi, A., and Booten, K., Biomacromolecules, 2001, vol. 2, no. 1, pp. 1–16. https://doi.org/10.1021/bm005642t
Golovin, A.I., Trofimov, A.N., Uzlov, G.A., Zhukova, I.P., Kiprianov, A.I., Prokhorchuk, T.I., and Kovalev, V.E., Lesokhimicheskie produkty sul’fattsellyuloznogo proizvodstva (Wood Chemical Products Sulfate Pulp Production), Moscow: Lesn. Prom-st’, 1988.
Evdokimov, A.N., Kurzin, A.V., Popova, L.M., and Franchuk, V.B., Eur. J. Wood Prod., 2021, vol. 79, no. 4, pp. 1027–1029. https://doi.org/10.1007/s00107-021-01663-9
Wang, S.-F., Furuno, T., and Cheng, Z., J. Wood Sci., 2001, vol. 47, no. 6, pp. 470–475. https://doi.org/10.1007/BF00767900
Torlopov, M.A., Udoratina, E.V., and Kuchin, A.V., Russ. J. Org. Chem., 2013, vol. 49, no. 5, pp. 702–706. https://doi.org/10.1134/S1070428013050114
Kurzin, A.V., Evdokimov, A.N., Pavlova, O.S., and Antipina, V.B., Russ. J. Appl. Chem., 2008, vol. 81, no. 12, pp. 2178–2179. https://doi.org/10.1134/S1070427208120288
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Translated from Zhurnal Prikladnoi Khimii, No. 2, pp. 147–150, February, 2023 https://doi.org/10.31857/S0044461823020020
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Kurzin, A.V., Evdokimov, A.N. & Il’ina, N.S. Esters of Inulin and Tall Oil Fatty Acids. Russ J Appl Chem 96, 143–145 (2023). https://doi.org/10.1134/S1070427223020028
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DOI: https://doi.org/10.1134/S1070427223020028