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Coagulating Ability of N,N-Diallyl-N,N-dimethylammonium Chloride-based Copolymers in the Separation of Rubbers of Various Grades

  • Macromolecular Compounds and Polymeric Materials
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Abstract

The study assessed the coagulating ability of copolymers N,N-diallyl-N,N-dimethylammonium chloride with acrylamide and maleic acid when separating styrene/butadiene and nitrile/butadiene rubbers from latexes. The effect of the consumption of these cationic polymers, the concentration of the dispersed phase and temperature on the completeness of rubber separation was studied. It was established that the completeness of styrene/butadiene rubber separation from latex is achieved at a 0.5 kg t–1 consumption of cationic copolymer with acrylamide, and that of butadiene/nitrile rubber is achieved at 22 kg t–1. The introduction of maleic acid units into the cationic copolymer ensures the complete separation of styrene/butadiene and nitrile/butadiene rubber from latex at a consumption of 0.3 and 8 kg t–1, respectively. Vulcanizates obtained from rubbers isolated using copolymers meet the requirements of State Standard GOST 15627–2019.

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REFERENCES

  1. Papkov, V.N., Rivin, E.M., Blinov, E.V., Butadien-stirol’nye kauchuki. Sintez i svoistva (Styrene-Butadiene Rubbers. Synthesis and Properties), Voronezh: Izd. VGUIT, 2015.

    Google Scholar 

  2. Averko-Antonovich, L.A., Averko-Antonovich, Yu.O., Davletbaeva, I.M., and Kirpichnikov, P.A., Khimiya i tekhnologiya sinteticheskogo kauchuka (Chemistry and Technology of Synthetic Rubber), Moscow: KolosS, 2008.

    Google Scholar 

  3. Orlov, Yu.N., Vestn. VGUIT, 2019, vol. 81, no. 1(79), pp. 318–324. https://doi.org/10.20914/2310-1202-2019-1-318-324

    Article  Google Scholar 

  4. Vostrikova, G.Yu. and Nikulin, S.S., Kationnye polielektrolity v tekhnologii vydeleniya kauchukov iz lateksa (Cationic Polyelectrolytes in the Technology of Extracting Rubber from Latex), Saarbrücken: Lambert Academic Publishing, 2020.

    Google Scholar 

  5. Odin, A.P. and Rachinskii, A.V., Kauchuk Rezina, 2009, no. 3, pp. 2–4. https://www.elibrary.ru/download/elibrary_22578638_85972878.pdf.

    Google Scholar 

  6. Pham, K.D, Gaidadin, A.N., Gorkovenko, D.A., and Navrotskiy, V.A., Russ. J. Appl. Chem., 2018, vol. 91, no. 2, pp. 320–324. https://doi.org/10.1134/S1070427218020234

    Article  Google Scholar 

  7. Vorobʹeva, A.I., Sagitova, D.R., Kolesov, S.V., and Monakov, Yu.B., Russ. J. Appl. Chem., 2009, vol. 82, no. 6, pp. 1046–1051. https://doi.org/10.1134/S1070427209060226

    Article  CAS  Google Scholar 

  8. Vorob’eva, A.I., Prochukhan, Yu.A., and Monakov, Yu.B., Vysokomolekulyar. Soedineniya, Ser. C, 2003, vol. 45, no. 12, pp. 2118–2136. https://www.elibrary.ru/item.asp?id=17255773

    Google Scholar 

  9. Abdiyev, K.Zh., Toktarbay, Zh., Zhenissova, A.Zh., Zhursumbaeva, M.B., Kainazarova, R.N., Nuraje, N., Colloids and Surfaces A: Physicochem. Eng. Aspects, 2015, vol. 480, pp. 228–235. https://doi.org/10.1016/j.colsurfa.2015.04.025

    Article  CAS  Google Scholar 

  10. Kuznetsova, O.N. and Sof’ina, S.Yu., Obshchaya khimicheskaya tekhnologiya polimerov: Uchebnoe posobie (General Chemical Technology of Polymers: Textbook), Kazan: Izd-vo Kazan. Gos. Tekhnol. Univ., 2010.

    Google Scholar 

  11. Poyarkova, T.N., Pikulin, S.S., Pugacheva, I.N., Kudrina, G.V., and Filimonova, O.N., Praktikum po kolloidnoi khimii lateksov (Workshop on Colloidal Chemistry of Latexes), Moscow: Izd. Dom Akademiya Estestvoznaniya, 2011.

    Google Scholar 

  12. Nikulin, S.S., Poyarkova, T.N., and and Misin, V.M., Russ. J. Appl. Chem., 2011, vol. 84, no. 5, pp. 882–887. https://doi.org/10.1134/S1070427211050247

    Article  CAS  Google Scholar 

  13. Papkov, V.N., Gusev, Yu.K., Blinov, E.V., and Rivin, E.M., Prom. Pr-vo Ispol’z. Elastomerov, 2010, no. 4, pp. 7–10. https://www.elibrary.ru/item.asp?id=16516219

    Google Scholar 

  14. Kryuchkova, N.V., Orlov, Y.N., Levanova, S.V., Russ. J. Appl. Chem., 2011, vol. 84, no. 11, pp. 1978–1982. https://doi.org/10.1134/S1070427211110243

    Article  CAS  Google Scholar 

  15. Pelssers, E., Coen, M., Stuart, M., and Fleer, G., Colloids and Surfaces, 1989, vol. 38. no. 1, pp. 15–25. https://doi.org/10.1016/0166-6622(89)80139-8

    Article  CAS  Google Scholar 

  16. Verezhnikov, V.N., Vostrikova, G.Yu., and Poyarkova, T.N., Russ. J. Appl. Chem., 2003, vol. 76, no. 8, pp. 1323–1326. https://doi.org/10.1023/B:RJAC.0000008311.63112.91

    Article  CAS  Google Scholar 

  17. Patent RU 2760489 C1 (Publ. 25.11.2021).

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Authors and Affiliations

  1. Voronezh State University of Engineering Technologies, 394036, Voronezh, Russia

    E. V. Churilina, S. S. Nikulin, V. N. Verezhnikov, G. V. Shatalov & M. V. Sergeev

Authors
  1. E. V. Churilina
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  2. S. S. Nikulin
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  3. V. N. Verezhnikov
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  4. G. V. Shatalov
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  5. M. V. Sergeev
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Contributions

M.V. Sergeev and V.N. Verezhnikov: performing coagulation experiments; E.V. Churilina and G.V. Shatalov: performing experiments on the synthesis of copolymers and analyzing their properties, searching the literature; S.S. Nikulin: determination of the purpose and objects of research with a selection of methods for conducting experiments on latex coagulation.

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Correspondence to E. V. Churilina.

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The authors declare that there are no conflicts of interest to disclose in this article.

Additional information

Translated from Zhurnal Prikladnoi Khimii, No. 1, pp. 53–59, August, 2023 https://doi.org/10.31857/S0044461823010073

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Churilina, E.V., Nikulin, S.S., Verezhnikov, V.N. et al. Coagulating Ability of N,N-Diallyl-N,N-dimethylammonium Chloride-based Copolymers in the Separation of Rubbers of Various Grades. Russ J Appl Chem 96, 44–49 (2023). https://doi.org/10.1134/S107042722301007X

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  • DOI: https://doi.org/10.1134/S107042722301007X

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