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Synthesis of a Molybdenum-Containing Mo2C/C Composite Material with Functionalized Carbon Nanotubes

  • Inorganic Synthesis and Industrial Inorganic Chemistry
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Abstract

The Mo2C/C composite material was synthesized by the sol-gel method using molybdenum blue dispersions. Carbon nanotubes treated with HCl (acid treatment) and a mixture of H2SO4 and HNO3 (liquid-phase oxidation) were used as the carbon support. Samples of finished supports and composites were characterized by X-ray phase analysis, transmission electron microscopy, infrared spectroscopy, and low temperature nitrogen adsorption to determine phase composition, surface morphology, and porous parameters. It was established that the content of molybdenum carbide in a composite material is affected by the electrical surface properties of carbon nanotubes and molybdenum blue nanoparticles.

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ACKNOWLEDGMENTS

Studies of the properties of materials (low-temperature nitrogen adsorption and infrared spectroscopy) were carried out at the Center for Collective Use of the Mendeleev University of Chemical Technology of Russia .

Funding

This work was supported by the Russian Science Foundation (grant no. 21-73-00303).

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Authors and Affiliations

  1. Mendeleev Russian University of Chemical Technology, 125047, Moscow, Russia

    M. A. Myachina, N. N. Gavrilova, V. A. D’yakonov & V. V. Nazarov

Authors
  1. M. A. Myachina
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  2. N. N. Gavrilova
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  3. V. A. D’yakonov
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  4. V. V. Nazarov
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Contributions

M.A. Myachina, N.N. Gavrilova, and V.V. Nazarov: planning of work and setting up experiments; M.A. Myachina: synthesis of Mo2C/carbon nanotubes samples and carrying out adsorption studies; M.A. Myachina, N.N. Gavrilova, and V.A. Dyakonov: conducting research by low-temperature nitrogen adsorption method, infrared spectroscopy, transmission electron microscopy, and X-ray phase analysis. All authors participated in the preparation, discussion and writing of the article text.

Corresponding author

Correspondence to M. A. Myachina.

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The authors declare that they have no conflict of interest requiring disclosure in this article.

Additional information

Translated from Zhurnal Prikladnoi Khimii, No. 1, pp. 12–20, August, 2023 https://doi.org/10.31857/S0044461823010024

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Myachina, M.A., Gavrilova, N.N., D’yakonov, V.A. et al. Synthesis of a Molybdenum-Containing Mo2C/C Composite Material with Functionalized Carbon Nanotubes. Russ J Appl Chem 96, 8–15 (2023). https://doi.org/10.1134/S1070427223010020

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  • DOI: https://doi.org/10.1134/S1070427223010020

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