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Synthesis of CuO–Cu4O3 Composite in Combustion Reactions of Nitrate–Organic Precursors

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Abstract

A CuO–Cu4O3-based composite was synthesized in the combustion reactions of nitrate–organic precursors using various fuel additives (glycerol, citric acid, ovalbumin, and urea). The resulting powders were examined by X-ray phase analysis, scanning electron microscopy, and low-temperature nitrogen adsorption and tested as components of ceramics and photocatalysts. It was found that a change in the nature of the fuel additive does not lead to a change in the phase composition, but affects the specific surface area of the samples. A regularity between the particle size and the dielectric parameters of the obtained CuO + Cu4O3 was revealed. It was established that all samples have photocatalytic activity towards the dye rhodamine B, and samples with a large specific surface area demonstrate high sorption property.

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Funding

The work was carried out within the framework of the state task of the Ministry of Science and Higher Education of the Russian Federation, project no. 0092-2019-0003.

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Authors and Affiliations

  1. Krestov Institute of Solution Chemistry, Russian Academy of Sciences, 153045, Ivanovo, Russia

    A. V. Evdokimova, A. S. Kraev, N. A. Sirotkin, A. V. Khlyustova & A. V. Agafonov

  2. Ivanovo State University of Chemistry and Technology, 153000, Ivanovo, Russia

    A. I. Larionov

Authors
  1. A. V. Evdokimova
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  2. A. I. Larionov
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  3. A. S. Kraev
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  4. N. A. Sirotkin
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  5. A. V. Khlyustova
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  6. A. V. Agafonov
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Contributions

A.V. Agafonov and A.V. Evdokimova developed the experimental technique; A.V. Evdokimova, A.I. Larionov synthesized samples and analyzed the literature; A.S. Kraev, N.A. Sirotkin measured the dielectric and photocatalytic characteristics of the obtained samples; A.V. Agafonov, A.V. Khlyustova formulated the concept of the article.

Corresponding author

Correspondence to A. V. Khlyustova.

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The authors declare no conflict of interest requiring disclosure in this article.

Additional information

Translated from Zhurnal Prikladnoi Khimii, Nos. 11–12, pp. 1488–1494, August, 2022 https://doi.org/10.31857/S0044461822110147

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Evdokimova, A.V., Larionov, A.I., Kraev, A.S. et al. Synthesis of CuO–Cu4O3 Composite in Combustion Reactions of Nitrate–Organic Precursors. Russ J Appl Chem 95, 1834–1839 (2022). https://doi.org/10.1134/S1070427222120114

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